Zhouping Wu , Guanghui Lv , Zheng Lin , Jiangyan Tang , Jian Chen , Jianghong Liu , Li Hai , Yong Wu
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引用次数: 0
摘要
有报告称，通过过渡金属催化剂和光催化剂的结合，可在室温下构建 N-融合多环化合物。这项新工作成功实现了 LED 照射下碘化铵酰化物的 C-H 活化。该策略具有广泛的底物范围和理想的官能团耐受性。我们的工作将有助于构建各种杂环化合物。
Mild construction of N-fused polycyclic compounds via Rh(III)/EosinY co-catalyze C−H activation
The construction of N-fused polycyclic compounds at room temperature via the combination of transition-metal catalyst and photocatalyst has been reported. This novel work has successfully realized LED irradiated C−H activation of iodonium ylides. The strategy shows wide substrate scope and ideal functional group tolerance. Our work would be useful for the construction of various heterocyclic compounds.
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