E. A. Gomaa, M. Diab, A. El-Sonbati, Hamed M Abuo Elnader, A. M. Helm
{"title":"用玻碳工作电极研究CuBr2与卡巴嗪720 (LC)在氯化钠中相互作用的电化学溶剂化参数(循环伏安法)","authors":"E. A. Gomaa, M. Diab, A. El-Sonbati, Hamed M Abuo Elnader, A. M. Helm","doi":"10.26655/JMCHEMSCI.2019.3.7","DOIUrl":null,"url":null,"abstract":"he redox mechanisms were examined for Copper bromide in the absence and presence of (LC) using cyclic voltammetry. The mechanisms of reduction and oxidation were examined while using new glassy carbon electrode prepared in laboratory from pure carbon piece jointed with copper wire and isolated by heat shrink polymer to avoid contact with solutions. In order to explain the type of the used reaction in electrochemical study, the complexation stability constants and Gibbs free energies of complex formation obtained from the interaction of CuBr2 with (LC) were obtained from the experimental part and their values were discussed. The prepared galssy carbon electrode was polished with Al2O3 andput in a woolen clear piece, washed and used for cyclic voltammetry measurements.","PeriodicalId":16365,"journal":{"name":"Journal of Medicinal and Chemical Sciences","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2019-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrochemical Solvation Parameters for The Interaction of CuBr2 With Carbazine 720 (LC) in NaClO4 Using Glassy Carbon working electrode (cyclic voltammetry)\",\"authors\":\"E. A. Gomaa, M. Diab, A. El-Sonbati, Hamed M Abuo Elnader, A. M. Helm\",\"doi\":\"10.26655/JMCHEMSCI.2019.3.7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"he redox mechanisms were examined for Copper bromide in the absence and presence of (LC) using cyclic voltammetry. The mechanisms of reduction and oxidation were examined while using new glassy carbon electrode prepared in laboratory from pure carbon piece jointed with copper wire and isolated by heat shrink polymer to avoid contact with solutions. In order to explain the type of the used reaction in electrochemical study, the complexation stability constants and Gibbs free energies of complex formation obtained from the interaction of CuBr2 with (LC) were obtained from the experimental part and their values were discussed. The prepared galssy carbon electrode was polished with Al2O3 andput in a woolen clear piece, washed and used for cyclic voltammetry measurements.\",\"PeriodicalId\":16365,\"journal\":{\"name\":\"Journal of Medicinal and Chemical Sciences\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Medicinal and Chemical Sciences\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.26655/JMCHEMSCI.2019.3.7\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Medicinal and Chemical Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.26655/JMCHEMSCI.2019.3.7","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Electrochemical Solvation Parameters for The Interaction of CuBr2 With Carbazine 720 (LC) in NaClO4 Using Glassy Carbon working electrode (cyclic voltammetry)
he redox mechanisms were examined for Copper bromide in the absence and presence of (LC) using cyclic voltammetry. The mechanisms of reduction and oxidation were examined while using new glassy carbon electrode prepared in laboratory from pure carbon piece jointed with copper wire and isolated by heat shrink polymer to avoid contact with solutions. In order to explain the type of the used reaction in electrochemical study, the complexation stability constants and Gibbs free energies of complex formation obtained from the interaction of CuBr2 with (LC) were obtained from the experimental part and their values were discussed. The prepared galssy carbon electrode was polished with Al2O3 andput in a woolen clear piece, washed and used for cyclic voltammetry measurements.