用玻碳工作电极研究CuBr2与卡巴嗪720 (LC)在氯化钠中相互作用的电化学溶剂化参数(循环伏安法)

E. A. Gomaa, M. Diab, A. El-Sonbati, Hamed M Abuo Elnader, A. M. Helm
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引用次数: 0

摘要

用循环伏安法研究了溴化铜在(LC)存在和不存在情况下的氧化还原机理。采用实验室制备的新型玻碳电极,将纯碳片与铜丝连接,用热缩聚合物隔离,避免与溶液接触,研究了还原氧化机理。为了解释电化学研究中使用的反应类型,从实验部分得到了CuBr2与(LC)相互作用的络合稳定常数和络合物形成的吉布斯自由能,并对它们的取值进行了讨论。将制备好的玻碳电极用Al2O3抛光,置于羊毛透明片中,洗涤后用于循环伏安法测量。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Electrochemical Solvation Parameters for The Interaction of CuBr2 With Carbazine 720 (LC) in NaClO4 Using Glassy Carbon working electrode (cyclic voltammetry)
he redox mechanisms were examined for Copper bromide in the absence and presence of (LC) using cyclic voltammetry. The mechanisms of reduction and oxidation were examined  while using new glassy carbon electrode prepared in laboratory from pure carbon piece jointed with copper wire and isolated by heat shrink polymer to avoid contact with solutions. In order to explain the type of the used reaction in electrochemical study, the complexation stability constants and Gibbs free energies of complex formation obtained from the interaction of CuBr2 with (LC) were obtained from the experimental part and their values were discussed. The prepared galssy carbon electrode was polished with Al2O3 andput in a woolen clear piece, washed and used for cyclic voltammetry measurements.
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