{"title":"反式二氯(丙烷-1,3-二胺)铑(III)的溴化物交换和碱水解动力学","authors":"Alison J. Thirst, D. Huw Vaughan","doi":"10.1016/0022-1902(81)80637-9","DOIUrl":null,"url":null,"abstract":"<div><p>The kinetics of the bromide interchange and base hydrolysis of <em>trans</em>-(Rh(tn)<sub>2</sub>Cl<sub>2</sub>)<sup>+</sup>, (tn=propane-1,3-diamine) have been studied. For the bromide interchange the observed pseudo first order rate constant is independent of bromide ion concentration up to 0.2 mol dm<sup>−3</sup>, whereas for the base hydrolysis the observed pseudo first order rate constant is given by <em>k</em><sub>obs</sub> = <em>k</em><sub>1</sub> + <em>k</em><sub>2</sub>(OH<sup>−</sup>) for hydroxide ion concentrations up to 1.0 mol dm<sup>−3</sup>.</p><p>The activation parameters for these two reactions have been determined and are compared with those for similar reactions of other analogous complexes.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 11","pages":"Pages 2889-2892"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80637-9","citationCount":"0","resultStr":"{\"title\":\"The kinetics of the bromide interchange and base hydrolysis of trans-dichlorobis (propane-1,3-diamine) rhodium (III)\",\"authors\":\"Alison J. Thirst, D. Huw Vaughan\",\"doi\":\"10.1016/0022-1902(81)80637-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The kinetics of the bromide interchange and base hydrolysis of <em>trans</em>-(Rh(tn)<sub>2</sub>Cl<sub>2</sub>)<sup>+</sup>, (tn=propane-1,3-diamine) have been studied. For the bromide interchange the observed pseudo first order rate constant is independent of bromide ion concentration up to 0.2 mol dm<sup>−3</sup>, whereas for the base hydrolysis the observed pseudo first order rate constant is given by <em>k</em><sub>obs</sub> = <em>k</em><sub>1</sub> + <em>k</em><sub>2</sub>(OH<sup>−</sup>) for hydroxide ion concentrations up to 1.0 mol dm<sup>−3</sup>.</p><p>The activation parameters for these two reactions have been determined and are compared with those for similar reactions of other analogous complexes.</p></div>\",\"PeriodicalId\":16275,\"journal\":{\"name\":\"Journal of Inorganic and Nuclear Chemistry\",\"volume\":\"43 11\",\"pages\":\"Pages 2889-2892\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-1902(81)80637-9\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inorganic and Nuclear Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0022190281806379\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281806379","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The kinetics of the bromide interchange and base hydrolysis of trans-dichlorobis (propane-1,3-diamine) rhodium (III)
The kinetics of the bromide interchange and base hydrolysis of trans-(Rh(tn)2Cl2)+, (tn=propane-1,3-diamine) have been studied. For the bromide interchange the observed pseudo first order rate constant is independent of bromide ion concentration up to 0.2 mol dm−3, whereas for the base hydrolysis the observed pseudo first order rate constant is given by kobs = k1 + k2(OH−) for hydroxide ion concentrations up to 1.0 mol dm−3.
The activation parameters for these two reactions have been determined and are compared with those for similar reactions of other analogous complexes.
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