{"title":"钒锑氧化物催化丙烷和丙烯氨氧化的机理","authors":"S. Buchholz, H. Zanthoff","doi":"10.1021/bk-1996-0638.ch019","DOIUrl":null,"url":null,"abstract":"The present work aimed at the elucidation of the reaction mechanism of the ammoxidation of propane and propene over a VSb 5 O x catalyst. Information on intermediate products and active sites were obtained by studying the interaction of NH 3 , propane and NH 3 , propene and NH 3 , as well as acrolein and NH 3 with a VSb 5 O x catalyst applying a vacuum transient technique","PeriodicalId":20402,"journal":{"name":"Preprints-American Chemical Society Division of Petroleum Chemistry","volume":"35 1","pages":"210-213"},"PeriodicalIF":0.0000,"publicationDate":"1996-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mechanism of catalytic ammoxidation of propane and propene over vanadium-antimony oxides\",\"authors\":\"S. Buchholz, H. Zanthoff\",\"doi\":\"10.1021/bk-1996-0638.ch019\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The present work aimed at the elucidation of the reaction mechanism of the ammoxidation of propane and propene over a VSb 5 O x catalyst. Information on intermediate products and active sites were obtained by studying the interaction of NH 3 , propane and NH 3 , propene and NH 3 , as well as acrolein and NH 3 with a VSb 5 O x catalyst applying a vacuum transient technique\",\"PeriodicalId\":20402,\"journal\":{\"name\":\"Preprints-American Chemical Society Division of Petroleum Chemistry\",\"volume\":\"35 1\",\"pages\":\"210-213\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1996-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Preprints-American Chemical Society Division of Petroleum Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1021/bk-1996-0638.ch019\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Preprints-American Chemical Society Division of Petroleum Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1021/bk-1996-0638.ch019","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
本文旨在阐明在vsb5 O x催化剂上丙烷和丙烯氨氧化的反应机理。采用真空瞬态技术研究了nh3、丙烷与nh3、丙烯与nh3、丙烯与nh3以及丙烯与nh3与vsb5o x催化剂的相互作用,得到了中间产物和活性位点的信息
Mechanism of catalytic ammoxidation of propane and propene over vanadium-antimony oxides
The present work aimed at the elucidation of the reaction mechanism of the ammoxidation of propane and propene over a VSb 5 O x catalyst. Information on intermediate products and active sites were obtained by studying the interaction of NH 3 , propane and NH 3 , propene and NH 3 , as well as acrolein and NH 3 with a VSb 5 O x catalyst applying a vacuum transient technique