Cassidy van Vuuren , Ao Zhang , James T. Hinkley , Chris W. Bumby , Matthew J. Watson
{"title":"新西兰氢炼铁的潜力","authors":"Cassidy van Vuuren , Ao Zhang , James T. Hinkley , Chris W. Bumby , Matthew J. Watson","doi":"10.1016/j.clce.2022.100075","DOIUrl":null,"url":null,"abstract":"<div><p>Globally, iron and steel production is responsible for approximately 6.3% of global man-made carbon dioxide emissions, because coal is used as both the combustion fuel and chemical reductant. Hydrogen reduction of iron ore offers a potential alternative ‘near-zero-CO<sub>2</sub>’ route, if renewable electrical power is used for both hydrogen electrolysis and reactor heating. This paper discusses key technoeconomic considerations for establishing a hydrogen direct reduced iron (H<sub>2</sub>-DRI) plant in New Zealand. The location and availability of firm renewable electricity generation is described, the experimental feasibility of reducing locally-sourced titanomagnetite ironsand in hydrogen is shown, and a high-level process flow diagram for a counter-flow electrically heated H<sub>2</sub>-DRI process is developed. The minimum hydrogen composition of the reactor off-gas is 46%, necessitating the inclusion of a hydrogen recycle loop to maximise chemical utilisation of hydrogen and minimize costs. A total electrical energy requirement of 3.24 MWh per tonne of H<sub>2</sub>-DRI is obtained for the base-case process considered here. Overall, a maximum input electricity cost of no more than US$80 per MWh at the plant is required to be cost-competitive with existing carbothermic DRI processes. Production cost savings could be achieved through realistic future improvements in electrolyser efficiency (∼ US$5 per tonne of H<sub>2</sub>-DRI) and heat exchanger (∼US$3 per tonne). We conclude that commercial H<sub>2</sub>-DRI production in New Zealand is entirely feasible, but will ultimately depend upon the price paid for firm electrical power at the plant.</p></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"4 ","pages":"Article 100075"},"PeriodicalIF":0.0000,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772782322000730/pdfft?md5=6d2d8cac15a4d9553e69123e9e57e362&pid=1-s2.0-S2772782322000730-main.pdf","citationCount":"1","resultStr":"{\"title\":\"The potential for hydrogen ironmaking in New Zealand\",\"authors\":\"Cassidy van Vuuren , Ao Zhang , James T. Hinkley , Chris W. Bumby , Matthew J. Watson\",\"doi\":\"10.1016/j.clce.2022.100075\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Globally, iron and steel production is responsible for approximately 6.3% of global man-made carbon dioxide emissions, because coal is used as both the combustion fuel and chemical reductant. Hydrogen reduction of iron ore offers a potential alternative ‘near-zero-CO<sub>2</sub>’ route, if renewable electrical power is used for both hydrogen electrolysis and reactor heating. This paper discusses key technoeconomic considerations for establishing a hydrogen direct reduced iron (H<sub>2</sub>-DRI) plant in New Zealand. The location and availability of firm renewable electricity generation is described, the experimental feasibility of reducing locally-sourced titanomagnetite ironsand in hydrogen is shown, and a high-level process flow diagram for a counter-flow electrically heated H<sub>2</sub>-DRI process is developed. The minimum hydrogen composition of the reactor off-gas is 46%, necessitating the inclusion of a hydrogen recycle loop to maximise chemical utilisation of hydrogen and minimize costs. A total electrical energy requirement of 3.24 MWh per tonne of H<sub>2</sub>-DRI is obtained for the base-case process considered here. Overall, a maximum input electricity cost of no more than US$80 per MWh at the plant is required to be cost-competitive with existing carbothermic DRI processes. Production cost savings could be achieved through realistic future improvements in electrolyser efficiency (∼ US$5 per tonne of H<sub>2</sub>-DRI) and heat exchanger (∼US$3 per tonne). We conclude that commercial H<sub>2</sub>-DRI production in New Zealand is entirely feasible, but will ultimately depend upon the price paid for firm electrical power at the plant.</p></div>\",\"PeriodicalId\":100251,\"journal\":{\"name\":\"Cleaner Chemical Engineering\",\"volume\":\"4 \",\"pages\":\"Article 100075\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2772782322000730/pdfft?md5=6d2d8cac15a4d9553e69123e9e57e362&pid=1-s2.0-S2772782322000730-main.pdf\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Cleaner Chemical Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2772782322000730\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cleaner Chemical Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2772782322000730","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The potential for hydrogen ironmaking in New Zealand
Globally, iron and steel production is responsible for approximately 6.3% of global man-made carbon dioxide emissions, because coal is used as both the combustion fuel and chemical reductant. Hydrogen reduction of iron ore offers a potential alternative ‘near-zero-CO2’ route, if renewable electrical power is used for both hydrogen electrolysis and reactor heating. This paper discusses key technoeconomic considerations for establishing a hydrogen direct reduced iron (H2-DRI) plant in New Zealand. The location and availability of firm renewable electricity generation is described, the experimental feasibility of reducing locally-sourced titanomagnetite ironsand in hydrogen is shown, and a high-level process flow diagram for a counter-flow electrically heated H2-DRI process is developed. The minimum hydrogen composition of the reactor off-gas is 46%, necessitating the inclusion of a hydrogen recycle loop to maximise chemical utilisation of hydrogen and minimize costs. A total electrical energy requirement of 3.24 MWh per tonne of H2-DRI is obtained for the base-case process considered here. Overall, a maximum input electricity cost of no more than US$80 per MWh at the plant is required to be cost-competitive with existing carbothermic DRI processes. Production cost savings could be achieved through realistic future improvements in electrolyser efficiency (∼ US$5 per tonne of H2-DRI) and heat exchanger (∼US$3 per tonne). We conclude that commercial H2-DRI production in New Zealand is entirely feasible, but will ultimately depend upon the price paid for firm electrical power at the plant.