阴离子表面活性剂在沥青覆盖粘土上的吸附

B. Siffert, A. Jada, E. Wersinger
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引用次数: 7

摘要

研究了饱和水甲苯在Na -高岭石、Ca2 -高岭石、Na -伊利石和Ca2 -伊利石粘土上对沥青的吸附。研究发现,在Na -和Ca2 -交换形式中,高岭石表面比伊利石吸附更多的沥青。研究了十二烷基苯磺酸钠(SDBS)和十二烷基硫酸钠(SDS)在不同沥青覆盖粘土上的吸附作用。等温线的形状取决于沥青-粘土基质,并且表明超过CMC的SDBS的吸附量要低得多。用分光光度法测定了SDS和SDS表面活性剂对不同粘土中沥青的解吸作用。SDS对沥青的解吸率比SDS表面活性剂的解吸率高2倍。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Anionic surfactant adsorption on to asphalt-covered clays

Asphalt adsorption from from water-saturated tolene on Na kaolinite, Ca2− kaolinite, Na illite and Ca2− illite clays was investigated. It was found that the kaolinite surface adsorbed more asphalt than illite for both the Na -and the Ca2− exchanged forms. Adsorption from aqueous solutions of sodium dodecylbenzenesulphonate (SDBS) and sodium dodecyl sulphate (SDS) on various asphalt-covered clays was also studied. The shape of the isotherms depended on the asphalt-clay substrate and showed a much lower adsorption of SDBS beyond the CMC. Desorption of asphalt from various clays with SDBS and SDS surfactants was measured spectrophotometrically. The percentage weight of asphalt desorbed with SDBS was twofold higher than that desorbed with SDS surfactant.

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