脱烯官能化：通过基于氧化还原的自由基过程将烯的 C(sp3)-C(sp2) 键转化为 C(sp3)-X 键。

IF 5 1区物理与天体物理 Q1 PHYSICS, PARTICLES & FIELDS

Journal of High Energy Physics Pub Date : 2024-01-01 Epub Date: 2023-04-12 DOI:10.1055/a-2044-4571

Brady W Dehnert, Jeremy H Dworkin, Ohyun Kwon

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引用次数: 0

摘要

本综述重点介绍脱烯官能化的历史和最新进展。通过这种解构策略，可在温和、稳健的条件下进行自由基官能化。所述反应具有高效率和良好的立体选择性，可容忍多种官能团，并可在几分钟内完成。通过裂解萜类和萜类衍生前体的 C(sp3)-C(sp2) 键，可以快速实现天然产品的多样化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Dealkenylative Functionalizations: Conversion of Alkene C(sp³)-C(sp²) Bonds into C(sp³)-X Bonds via Redox-Based Radical Processes.

This review highlights the history and recent advances in dealkenylative functionalization. Through this deconstructive strategy, radical functionalizations occur under mild, robust conditions. The reactions described proceed with high efficiency, good stereoselectivity, tolerate many functional groups, and are completed within a matter of minutes. By cleaving the C(sp³)-C(sp²) bond of terpenes and terpenoid-derived precursors, rapid diversification of natural products is possible.

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来源期刊

Journal of High Energy Physics PHYSICS, PARTICLES & FIELDS-

CiteScore

10.00

自引率

46.30%

发文量

2107

审稿时长

12 weeks

期刊介绍： The aim of the Journal of High Energy Physics (JHEP) is to ensure fast and efficient online publication tools to the scientific community, while keeping that community in charge of every aspect of the peer-review and publication process in order to ensure the highest quality standards in the journal. Consequently, the Advisory and Editorial Boards, composed of distinguished, active scientists in the field, jointly establish with the Scientific Director the journal''s scientific policy and ensure the scientific quality of accepted articles. JHEP presently encompasses the following areas of theoretical and experimental physics: Collider Physics Underground and Large Array Physics Quantum Field Theory Gauge Field Theories Symmetries String and Brane Theory General Relativity and Gravitation Supersymmetry Mathematical Methods of Physics Mostly Solvable Models Astroparticles Statistical Field Theories Mostly Weak Interactions Mostly Strong Interactions Quantum Field Theory (phenomenology) Strings and Branes Phenomenological Aspects of Supersymmetry Mostly Strong Interactions (phenomenology).