生物化学相关分子的阿秒光谱学

IF 5.9 2区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY
F. Calegari, A. Trabattoni, E. Månsson, J. Greenwood, P. Decleva, F. Martín, M. Nisoli
{"title":"生物化学相关分子的阿秒光谱学","authors":"F. Calegari, A. Trabattoni, E. Månsson, J. Greenwood, P. Decleva, F. Martín, M. Nisoli","doi":"10.1393/NCR/I2018-10150-2","DOIUrl":null,"url":null,"abstract":"Summary. — Understanding the role of the electron dynamics in the photochemistry of bio-chemically relevant molecules is key to getting access to the fundamental physical processes leading to damage, mutation and, more generally, to the alteration of the fi nal biological functions. Sudden ionization of a large molecule has been proven to activate a sub-femtosecond charge fl ow throughout the molecular backbone, purely guided by electronic coherences, which could ultimately a ff ect the photochemical response of the molecule at later times. We can follow this ultrafast charge fl ow in realtime by exploiting the extreme time resolution provided by attosecond light sources. In this work recent advances in attosecond molecular physics are presented with particular focus on the investigation of bio-relevant","PeriodicalId":54452,"journal":{"name":"Rivista Del Nuovo Cimento","volume":"36 1","pages":"415-461"},"PeriodicalIF":5.9000,"publicationDate":"2018-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Attosecond spectroscopy of bio-chemically relevant molecules\",\"authors\":\"F. Calegari, A. Trabattoni, E. Månsson, J. Greenwood, P. Decleva, F. Martín, M. Nisoli\",\"doi\":\"10.1393/NCR/I2018-10150-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Summary. — Understanding the role of the electron dynamics in the photochemistry of bio-chemically relevant molecules is key to getting access to the fundamental physical processes leading to damage, mutation and, more generally, to the alteration of the fi nal biological functions. Sudden ionization of a large molecule has been proven to activate a sub-femtosecond charge fl ow throughout the molecular backbone, purely guided by electronic coherences, which could ultimately a ff ect the photochemical response of the molecule at later times. We can follow this ultrafast charge fl ow in realtime by exploiting the extreme time resolution provided by attosecond light sources. In this work recent advances in attosecond molecular physics are presented with particular focus on the investigation of bio-relevant\",\"PeriodicalId\":54452,\"journal\":{\"name\":\"Rivista Del Nuovo Cimento\",\"volume\":\"36 1\",\"pages\":\"415-461\"},\"PeriodicalIF\":5.9000,\"publicationDate\":\"2018-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Rivista Del Nuovo Cimento\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1393/NCR/I2018-10150-2\",\"RegionNum\":2,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"PHYSICS, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Rivista Del Nuovo Cimento","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1393/NCR/I2018-10150-2","RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"PHYSICS, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 2

摘要

总结。-了解电子动力学在生物化学相关分子光化学中的作用,是了解导致损伤、突变以及更广泛地说,最终生物功能改变的基本物理过程的关键。一个大分子的突然电离已被证明可以激活亚飞秒的电荷流,完全由电子相干引导,这可能最终影响分子在以后的光化学反应。通过利用阿秒光源提供的极端时间分辨率,我们可以实时跟踪这种超快电荷流。本文介绍了近年来阿秒分子物理学的研究进展,重点介绍了生物相关的研究进展
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Attosecond spectroscopy of bio-chemically relevant molecules
Summary. — Understanding the role of the electron dynamics in the photochemistry of bio-chemically relevant molecules is key to getting access to the fundamental physical processes leading to damage, mutation and, more generally, to the alteration of the fi nal biological functions. Sudden ionization of a large molecule has been proven to activate a sub-femtosecond charge fl ow throughout the molecular backbone, purely guided by electronic coherences, which could ultimately a ff ect the photochemical response of the molecule at later times. We can follow this ultrafast charge fl ow in realtime by exploiting the extreme time resolution provided by attosecond light sources. In this work recent advances in attosecond molecular physics are presented with particular focus on the investigation of bio-relevant
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Rivista Del Nuovo Cimento
Rivista Del Nuovo Cimento 物理-物理:综合
CiteScore
9.50
自引率
2.20%
发文量
11
审稿时长
>12 weeks
期刊介绍: La Rivista del Nuovo Cimento is an international peer-reviewed journal. It publishes monographs in all fields of physics. These monographies aim at presenting the state of the art of topical subjects of relevant interest for the community. Usually, authors are invited and topics suggested by the Deputy Editors-in-Chief, but also spontaneous submissions are examined.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信