Ulises Carrillo, Antonio Francés-Monerris, Anil Reddy Marri, Cristina Cebrián* and Philippe C. Gros*,
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Substituent-Induced Control of fac/mer Isomerism in Azine-NHC Fe(II) Complexes
The stereoselective synthesis of geometrical iron(II) complexes bearing azine-NHC ligands is described. Facial and meridional selectivity is achieved as a function of the steric demand of the azine unit, with no remarkable influence of the carbene nature. More specifically, meridional complexes are obtained upon selecting bulky 5-mesityl-substituted pyridyl coordinating units. Unexpectedly, increase of the steric hindrance in the α position with respect to the N coordinating atom results in an exclusive facial configuration, which is in stark contrast to the meridional selectivity induced by other reported α-substituted bidentate ligands. Investigation of the structure and the optical and electrochemical properties of the here-described complexes has revealed the non-negligible effect of the fac/mer ligand configuration around the metal center.
期刊介绍：
ACS Organic & Inorganic Au is an open access journal that publishes original experimental and theoretical/computational studies on organic organometallic inorganic crystal growth and engineering and organic process chemistry. Short letters comprehensive articles reviews and perspectives are welcome on topics that include:Organic chemistry Organometallic chemistry Inorganic Chemistry and Organic Process Chemistry.
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