在一个高效的Z-Scheme光催化剂的原子水平上揭示界面电荷迁移途径

IF 16.1 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Dr. Pengfei Wang, Yueshuang Mao, Dr. Lina Li, Prof. Zhurui Shen, Xiao Luo, Prof. Kaifeng Wu, Dr. Pengfei An, Prof. Haitao Wang, Lina Su, Prof. Yi Li, Prof. Sihui Zhan
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引用次数: 118

摘要

用1D CdS和2D CoS2构建的高效Z-scheme光催化体系在420 nm处具有5.54 mmol h−1 g−1的光催化析氢活性,表观量子效率为10.2%。更重要的是,揭示了其界面电荷迁移途径:电子通过Co-S5.8配位连接的过渡原子层有效地从CdS转移到CoS2,从而导致更多的光生载流子参与表面反应。此外,利用瞬态吸收光谱研究了CdS/CoS2中的电荷捕获和电荷转移过程,估计其电荷分离率约为91.5%,电荷分离态寿命约为(5.2±0.5)ns。该研究阐明了界面原子层在异质结中的关键作用,将有助于开发更高效的Z-scheme光催化体系。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Unraveling the Interfacial Charge Migration Pathway at the Atomic Level in a Highly Efficient Z-Scheme Photocatalyst

Unraveling the Interfacial Charge Migration Pathway at the Atomic Level in a Highly Efficient Z-Scheme Photocatalyst

A highly efficient Z-scheme photocatalytic system constructed with 1D CdS and 2D CoS2 exhibited high photocatalytic hydrogen-evolution activity of 5.54 mmol h−1 g−1 with an apparent quantum efficiency of 10.2 % at 420 nm. More importantly, its interfacial charge migration pathway was unraveled: The electrons are efficiently transferred from CdS to CoS2 through a transition atomic layer connected by Co–S5.8 coordination, thus resulting in more photogenerated carriers participating in surface reactions. Furthermore, the charge-trapping and charge-transfer processes were investigated by transient absorption spectroscopy, which gave an estimated charge-separation yield of approximately 91.5 % and a charge-separated-state lifetime of approximately (5.2±0.5) ns in CdS/CoS2. This study elucidates the key role of interfacial atomic layers in heterojunctions and will facilitate the development of more efficient Z-scheme photocatalytic systems.

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来源期刊
CiteScore
26.60
自引率
6.60%
发文量
3549
审稿时长
1.5 months
期刊介绍: Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.
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