奥本海默的第一篇论文:分子波段光谱和专业风格

D. Cassidy
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引用次数: 3

摘要

从20世纪早期开始,光谱学家将双原子分子发出的红外光谱归因于分子的量子振动和旋转模式。由于这些相对简单的运动,带谱提供了一种方便的第一种现象,用于应用1926年新量子力学的公式。在他1926年5月在剑桥完成的第一篇论文中,奥本海默在保罗·狄拉克的新量子换向子代数的基础上,给出了观测到的光谱线的频率和相对强度的推导。与此同时,Lucy Mensing利用矩阵力学发表了类似的推导,Edwin Fues利用波动力学也发表了类似的推导。对奥本海默的论文及其历史和科学背景的分析,可以让我们深入了解新量子力学及其在这一短暂的形式主义竞争时期的应用和接受,以及奥本海默后来的研究和出版风格的特点。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Oppenheimer's first paper: Molecular band spectra and a professional style
Beginning early in the 20th century spectroscopists attributed the infrared band spectra emitted by diatomic molecules to quantum vibration and rotation modes of the molecules. Because of these relatively simple motions, band spectra offered a convenient .rst phenomenon to which to apply formulations of the new quan-tum mechanics in 1926. In his .rst paper, completed in Cambridge in May 1926, Oppenheimer presented a derivation of the frequencies and relative intensities of the observed spectral lines on the basis of Paul Dirac9s new quantum commutator algebra. At the same time Lucy Mensing published a similar derivation utiliz-ing matrix mechanics, as did Edwin Fues utilizing wave mechanics. Analyses of Oppenheimer9s paper and of its historical and scienti.c contexts offer insights into the new quantum mechanics and its utilization and reception during this brief period of competing formalisms, and into the characteristic features of Oppenheimer9s later style of research and publication.
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