橡胶对碳塑料强度性能影响的研究

Pub Date : 2022-10-28 DOI:10.15407/knit2022.05.067
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引用次数: 0

摘要

弹性体的使用使我们能够有目的地改变环氧树脂成分的结构,这在很大程度上决定了其特性。特别感兴趣的是弹性体,如硅橡胶和聚氨酯橡胶。在制造碳纤维板的实验工作中,我们采用了手工成型加机械压制的方法。该技术经济,不需要大量的人工成本,与使用其他方法相比,材料消耗更少。研究了聚氨酯和硅橡胶作为改性剂对环氧树脂热固化抗冲击强度的影响。为了确定碳纤维的抗压强度,在MUP200万能试验机上对样品进行了测试。采用Charpy法测定了碳纤维的冲击强度。确定了聚氨酯和硅橡胶对环氧树脂性能的定性影响是相同的。当用聚氨酯橡胶改性碳纤维,其含量增加10%时,碳纤维的冲击强度最大可提高至215 kJ/m2,抗压强度显著提高,可达495 MPa。当该物质的含量为10%时,聚氨酯橡胶的效果最佳。橡胶增加材料强度和弹性的主要作用是,当少量碳纤维的冲击集中了大量的机械能时,橡胶是应力集中器,因此在与弹性体(橡胶)相邻的基体中产生裂纹。材料韧性的增加可能与橡胶分散相的形成有关,这使固化的环氧树脂的结构松动。
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Study of the influence of rubber on stremgth properties of carbon plastic
The use of elastomers allows us to purposefully change the structure of epoxy compositions, which largely determines the characteristics. Of particular interest are elastomers, such as silicone and polyurethane rubbers. In experimental works for the manufacture of carbon fiber plates, we used the method of manual molding with mechanical pressing. This technology is economical, does not require large labor costs, and less material consumption than when using other methods of formation. The effect of polyurethane and silicone rubbers as modifiers of increasing the impact strength of epoxy resin Etal-Inject-T hot curing has been studied. To determine the compressive strength of carbon fiber, the samples were tested on a universal test machine MUP200. The impact strength of carbon fiber was determined by the Charpy method. It is established that polyurethane and silicone rubbers have the same qualitative effect on the properties of epoxy resins. When modifying carbon fiber with polyurethane rubber with an increase in the content of up to 10%, the impact strength of carbon fiber increases to a maximum of 215 kJ/m2, with a significant increase in compressive strength up to 495 MPa. Optimal results were obtained with polyurethane rubber at 10% content of the substance. The main role of rubber in increasing the strength and elasticity of the material is that when the impact in a small amount of carbon fiber concentrates a lot of mechanical energy, the rubbers are stress concentrators, so the crack arises in the matrix adjacent to the elastomer (rubber). The increase in the toughness of the material can be associated with the formation of a dispersed phase of rubber, which loosens the structure of the cured epoxy resin.
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