耐热型HK钢(HK30Nb)在800℃下的氧化行为

IF 2.1 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING
Marie Romedenne, Bruce Pint, Michael Lance, Sebastien Dryepondt
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引用次数: 0

摘要

研究了激光粉末床熔合(LPBF)热处理的HK30Nb耐热钢与铸造钢在800℃空气和空气+ 10% H2O环境中的循环氧化行为。与粗晶高Mn的铸态HK30Nb相比,LPBF合金具有更细的微观组织和更低的Mn,在干燥空气中氧化速率更低,在空气+ 10% H2O中形成连续Cr2O3结垢速度更快。在温度循环过程中,合金机械强度的差异,以及它们适应高温和氧化诱导应力的能力,以及合金和形成的氧化物(LPBF只适用Cr2O3,铸造试样适用Cr2O3和MnCr2O4)之间热膨胀系数的差异,导致LPBF在800°C干燥空气中比铸造合金更大程度的剥落。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Oxidation Behavior of Heat-Resistant Type HK Steel (HK30Nb) at 800 °C

Oxidation Behavior of Heat-Resistant Type HK Steel (HK30Nb) at 800 °C

The cyclic oxidation behavior of HK30Nb heat-resistant steel processed by laser powder bed fusion (LPBF) was compared to its cast counterpart during exposures in air and air + 10% H2O at 800 °C. The specific finer microstructure and lower Mn of the LPBF alloy resulted in lower oxidation rates in dry air and faster establishment of a continuous Cr2O3 scale in air + 10% H2O compared to coarse-grained cast HK30Nb with higher Mn. Differences in alloy mechanical strength and therefore their ability to accommodate high temperature and oxidation-induced stresses as well as differences in thermal expansion coefficients between the alloy and the formed oxides (Cr2O3 only for the LPBF and Cr2O3 and MnCr2O4 for the cast specimens) during temperature cycling were found to result in a greater extent of spallation for the LPBF than for the cast alloy in dry air at 800 °C.

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来源期刊
Oxidation of Metals
Oxidation of Metals 工程技术-冶金工程
CiteScore
5.10
自引率
9.10%
发文量
47
审稿时长
2.2 months
期刊介绍: Oxidation of Metals is the premier source for the rapid dissemination of current research on all aspects of the science of gas-solid reactions at temperatures greater than about 400˚C, with primary focus on the high-temperature corrosion of bulk and coated systems. This authoritative bi-monthly publishes original scientific papers on kinetics, mechanisms, studies of scales from structural and morphological viewpoints, transport properties in scales, phase-boundary reactions, and much more. Articles may discuss both theoretical and experimental work related to gas-solid reactions at the surface or near-surface of a material exposed to elevated temperatures, including reactions with oxygen, nitrogen, sulfur, carbon and halogens. In addition, Oxidation of Metals publishes the results of frontier research concerned with deposit-induced attack. Review papers and short technical notes are encouraged.
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