一种简化碱性燃料电池试验台

B. Aremo, M. O. Adeoye, I. Obioh
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引用次数: 2

摘要

在过去的四十年中,碱性燃料电池(AFC)在很大程度上被聚合物电解质膜燃料电池(PEMFC)和固体氧化物燃料电池(SOFC)所忽视。然而,由于PEMFC和SOFC的高成本和复杂性,近年来人们对AFC重新产生了兴趣。这项工作报告了与AFC电极测试和系统优化相关的定制测试夹具和电子仪器的设计。在设计中实现的功能包括实时电压测量单元(VMU),电子负载电路和电解质加热系统。验证实验表明,VMU的读数、能斯特方程预测和数字电压表的读数之间存在密切的一致性。电解质加热器系统的温度测量模块经过验证,其能够复制乙醇的冷却曲线,类似于从玻璃汞温度计获得的冷却曲线。介绍了其他试验台部件的材料选择、设计考虑和制造步骤,如钮扣电池试验装置和半圆柱形电解质加热器。利用该试验站对不同氢氧化钾(KOH)电解液温度和浓度条件下铝-空气AFC的极化特性进行了研究。研究表明,AFC电极的最佳电解液温度和浓度分别为70°C和4 M KOH。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Simplified Test Station for Alkaline Fuel Cell
For most of the last four decades, the alkaline fuel cell (AFC) has been largely overlooked in favor of the polymer electrolyte membrane fuel cell (PEMFC) and the solid oxide fuel cell (SOFC). However, the persistently high costs and complexities of the PEMFC and the SOFC have led to renewed interest in the AFC in recent times. This work reports the designs of custom test fixtures and electronics instrumentation relevant for AFC electrode testing and system optimization. Features implemented in the designs include a real-time voltage measurement unit (VMU), electronic load circuit, and electrolyte heater system. Validation experiments indicated a close agreement between the VMU’s readings, Nernst equation predictions, and readings from a digital voltmeter. The electrolyte heater system’s temperature measurement module was validated with its ability to replicate a cooling profile of ethanol similar to that obtained from a mercury-in-glass thermometer. Materials selection, design considerations, and fabrication steps for other test station components, such as the button-cell test apparatus and the half-cylinder electrolyte heater, were presented. The test station was used for polarization studies of aluminum-air AFC under different conditions of potassium hydroxide (KOH) electrolyte temperature and concentration. The studies revealed optimum values of electrolyte temperature and concentration for the AFC electrode to be 70 °C and 4 M KOH, respectively.
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来源期刊
自引率
0.00%
发文量
0
审稿时长
6-12 weeks
期刊介绍: The Journal of Fuel Cell Science and Technology publishes peer-reviewed archival scholarly articles, Research Papers, Technical Briefs, and feature articles on all aspects of the science, engineering, and manufacturing of fuel cells of all types. Specific areas of importance include, but are not limited to: development of constituent materials, joining, bonding, connecting, interface/interphase regions, and seals, cell design, processing and manufacturing, multi-scale modeling, combined and coupled behavior, aging, durability and damage tolerance, reliability, availability, stack design, processing and manufacturing, system design and manufacturing, power electronics, optimization and control, fuel cell applications, and fuels and infrastructure.
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