Libing Yao, Peichao Zou, Chunyang Wang, Jiahao Jiang, Lu Ma, Sha Tan, Kevin A. Beyer, Feng Xu, Enyuan Hu, Huolin L. Xin
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引用次数: 29
摘要
由于层状过渡金属氧化物在能量密度和成本方面的总体优势,它是钠离子电池极具吸引力的阴极。但其稳定性通常受到复杂的相变和氧氧化还原的影响,特别是在高压下工作时,导致结构稳定性差,容量损失大。本文提出了一种将高熵设计与超晶格稳定相结合的方法来延长层状阴极的循环寿命,提高层状阴极的倍率性能。结果表明,制备的高熵Na2/3Li1/6Fe1/6Co1/6Ni1/6Mn1/3O2阴极具有Li/过渡金属有序的超晶格结构,具有优异的电化学性能,且不受相变和氧氧化还原的影响。它具有高可逆容量(0.1℃时为171.2 mAh g−1),高能量密度(531 Wh kg−1),延长循环稳定性(90次循环时为89.3%,300次循环后为5c时为63.7%),以及出色的快速充电能力(10℃时为78 mAh g−1)。该策略将激发更合理的设计,以提高二次离子电池层状阴极的可靠性。
High-Entropy and Superstructure-Stabilized Layered Oxide Cathodes for Sodium-Ion Batteries
Layered transition metal oxides are appealing cathodes for sodium-ion batteries due to their overall advantages in energy density and cost. But their stabilities are usually compromised by the complicated phase transition and the oxygen redox, particularly when operating at high voltages, leading to poor structural stability and substantial capacity loss. Here an integrated strategy combing the high-entropy design with the superlattice-stabilization to extend the cycle life and enhance the rate capability of layered cathodes is reported. It is shown that the as-prepared high-entropy Na2/3Li1/6Fe1/6Co1/6Ni1/6Mn1/3O2 cathode enables a superlattice structure with Li/transition metal ordering and delivers excellent electrochemical performance that is not affected by the presence of phase transition and oxygen redox. It achieves a high reversible capacity (171.2 mAh g−1 at 0.1 C), a high energy density (531 Wh kg−1), extended cycling stability (89.3% capacity retention at 1 C for 90 cycles and 63.7% capacity retention at 5 C after 300 cycles), and excellent fast-charging capability (78 mAh g−1 at 10 C). This strategy would inspire more rational designs that can be leveraged to improve the reliability of layered cathodes for secondary-ion batteries.
期刊介绍:
Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small.
With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics.
The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.