[W(η - 2- phc2ph)3(NCMe)]与邻二苯基膦-苯乙烯和-烯丙苯的反应新的碳-碳双键和三键裂解和炔插入反应的证据

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 1996-01-01 DOI:10.1039/CC9960002431

G. Cairns, N. Carr, Michael J. Green, M. Mahon

引用次数: 15

摘要

[W(η - 2-PhC2Ph)3(NCMe)]与邻二苯基膦-苯乙烯或-烯丙基苯的反应导致新的碳-碳双键和三键断裂重组反应，或PhC2Ph进入碳氢键的异常插入反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene and -allylbenzene; evidence for novel carbon–carbon double and triple bond cleavage and alkyne insertion reactions

Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene or -allylbenzene leads to either novel reorganisation reactions involving cleavage of carbon–carbon double and triple bonds, or unusual insertion reactions by PhC2Ph into carbon–hydrogen bonds.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.