Xiaolei Deng, Ziqing Li, Fa Cao, Enliu Hong, Xiaosheng Fang
{"title":"用于可扩展紫外光通信设备的编织纤维光电探测器","authors":"Xiaolei Deng, Ziqing Li, Fa Cao, Enliu Hong, Xiaosheng Fang","doi":"10.1002/adfm.202213334","DOIUrl":null,"url":null,"abstract":"<p>Fibrous photodetectors (FPDs) have attracted great interest in wearable and consumer electronics, which is a lightweight and flexible tools to achieve efficient light information transmission. However, there is a necessary compromise between high optoelectronic performance and high-level integration. Herein, a woven optoelectronic keyboard consisting of 40 PD button units is extended and integrated from four individual FPDs, with the integration level expanding by 1000%. Each FPD is based on uniform type-II TiO<sub>2</sub>/Cs<sub>3</sub>Cu<sub>2</sub>I<sub>5</sub> heterojunction, which exhibits greatly reduced dark current by eight orders of magnitudes, large rectification ratio up to 33306@± 5V, high on–off ratio of 2.8 × 10<sup>4</sup>@−1 V and self-powered responsivity of 26.9 mA W<sup>−1</sup>. The vacuum-deposited Cs<sub>3</sub>Cu<sub>2</sub>I<sub>5</sub> nanoparticles finely passivate the massive defects and serve as a p-type hole transport layer to improve hole transfer efficiency, which greatly promotes the radial transport and collection of photogenerated electrons. Moreover, the photocurrent remains highly stable after bending and twisting states. Intriguingly, the woven optoelectronic keyboards successfully realize logic AND/OR, further identifying the UV light signal as a keying text signal (“A–Z” letters, “0–9” numbers, and four punctuations). This work not only provides a scalable strategy to reduce device redundancy but also shows the great potential of fibrous photodetectors for wearable optical communication.</p>","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"33 23","pages":""},"PeriodicalIF":18.5000,"publicationDate":"2023-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"17","resultStr":"{\"title\":\"Woven Fibrous Photodetectors for Scalable UV Optical Communication Device\",\"authors\":\"Xiaolei Deng, Ziqing Li, Fa Cao, Enliu Hong, Xiaosheng Fang\",\"doi\":\"10.1002/adfm.202213334\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Fibrous photodetectors (FPDs) have attracted great interest in wearable and consumer electronics, which is a lightweight and flexible tools to achieve efficient light information transmission. However, there is a necessary compromise between high optoelectronic performance and high-level integration. Herein, a woven optoelectronic keyboard consisting of 40 PD button units is extended and integrated from four individual FPDs, with the integration level expanding by 1000%. Each FPD is based on uniform type-II TiO<sub>2</sub>/Cs<sub>3</sub>Cu<sub>2</sub>I<sub>5</sub> heterojunction, which exhibits greatly reduced dark current by eight orders of magnitudes, large rectification ratio up to 33306@± 5V, high on–off ratio of 2.8 × 10<sup>4</sup>@−1 V and self-powered responsivity of 26.9 mA W<sup>−1</sup>. The vacuum-deposited Cs<sub>3</sub>Cu<sub>2</sub>I<sub>5</sub> nanoparticles finely passivate the massive defects and serve as a p-type hole transport layer to improve hole transfer efficiency, which greatly promotes the radial transport and collection of photogenerated electrons. Moreover, the photocurrent remains highly stable after bending and twisting states. Intriguingly, the woven optoelectronic keyboards successfully realize logic AND/OR, further identifying the UV light signal as a keying text signal (“A–Z” letters, “0–9” numbers, and four punctuations). This work not only provides a scalable strategy to reduce device redundancy but also shows the great potential of fibrous photodetectors for wearable optical communication.</p>\",\"PeriodicalId\":112,\"journal\":{\"name\":\"Advanced Functional Materials\",\"volume\":\"33 23\",\"pages\":\"\"},\"PeriodicalIF\":18.5000,\"publicationDate\":\"2023-02-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"17\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Functional Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/adfm.202213334\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Functional Materials","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/adfm.202213334","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 17
摘要
纤维光电探测器(FPDs)作为一种轻便、灵活的光信息传输工具,在可穿戴和消费电子领域引起了人们的极大兴趣。然而,在高光电性能和高集成度之间有一个必要的妥协。其中,一个由40个PD按键单元组成的编织式光电键盘由4个单独的fpga扩展和集成,集成水平扩大了1000%。每个FPD都基于均匀的ii型TiO2/Cs3Cu2I5异质结,其暗电流大大降低了8个数量级,整流比高达33306@±5V,通断比高达2.8 × 104@−1 V,自供电响应度为26.9 mA W−1。真空沉积的Cs3Cu2I5纳米粒子能很好地钝化大量缺陷,并作为p型空穴传输层,提高空穴传输效率,极大地促进了光生电子的径向传输和收集。此外,光电流在弯曲和扭曲状态后仍保持高度稳定。有趣的是,编织的光电键盘成功地实现了逻辑与/或,进一步将紫外光信号识别为键盘文本信号(“a - z”字母,“0-9”数字和四个标点符号)。这项工作不仅提供了一种可扩展的策略来减少设备冗余,而且还显示了纤维光电探测器在可穿戴光通信中的巨大潜力。
Woven Fibrous Photodetectors for Scalable UV Optical Communication Device
Fibrous photodetectors (FPDs) have attracted great interest in wearable and consumer electronics, which is a lightweight and flexible tools to achieve efficient light information transmission. However, there is a necessary compromise between high optoelectronic performance and high-level integration. Herein, a woven optoelectronic keyboard consisting of 40 PD button units is extended and integrated from four individual FPDs, with the integration level expanding by 1000%. Each FPD is based on uniform type-II TiO2/Cs3Cu2I5 heterojunction, which exhibits greatly reduced dark current by eight orders of magnitudes, large rectification ratio up to 33306@± 5V, high on–off ratio of 2.8 × 104@−1 V and self-powered responsivity of 26.9 mA W−1. The vacuum-deposited Cs3Cu2I5 nanoparticles finely passivate the massive defects and serve as a p-type hole transport layer to improve hole transfer efficiency, which greatly promotes the radial transport and collection of photogenerated electrons. Moreover, the photocurrent remains highly stable after bending and twisting states. Intriguingly, the woven optoelectronic keyboards successfully realize logic AND/OR, further identifying the UV light signal as a keying text signal (“A–Z” letters, “0–9” numbers, and four punctuations). This work not only provides a scalable strategy to reduce device redundancy but also shows the great potential of fibrous photodetectors for wearable optical communication.
期刊介绍:
Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week.
Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.