{"title":"准固态锂金属电池双稳定界面的多功能掺硅聚醚网络","authors":"Qi Zhang, Xiao Liu, Hao Li, Zhijie Guo, Tengfei Bian, Xuebing Zhu, Niannian Zhan, Yong Zhao","doi":"10.1002/smll.202106395","DOIUrl":null,"url":null,"abstract":"<p>Polymer-based quasi-solid-state electrolyte (QSE) is an effective means to solve the safety problem of lithium (Li) metal batteries, and stable solid-electrolyte-interface (SEI) layers between electrolyte and anode/cathode are highly required for their long-term stability. Herein, it is demonstrated that a silicon-doped polyether functions as a multifunctional unit, which can induce the formation of stable and robust SEI layers with rich Li<sub>x</sub>SiO<sub>y</sub> on both the surfaces of cathode and anode. It simultaneously solves the compatibility of electrolyte and electrodes in the quasi-solid-state Li-metal battery. Moreover, the robust polymer skeleton with a cross-linked network is beneficial to inhibit liquid volatilization and improve battery safety. The assembled Li|QSE|LiFePO<sub>4</sub> batteries show a capacity retention rate as high as 97.5% after 400 cycles at 1 C (30 °C), and reach 78.1% after 1000 cycles. Furthermore, there is almost no attenuation of reversible capacity after 100 cycles for the assembled Li|QSE|LiNi<sub>0.8</sub>Mn<sub>0.1</sub>Co<sub>0.1</sub>O<sub>2</sub> batteries. The concept of silicon-doped polymer with a crosslinking structure provides an important strategy for designing solid-state or quasi-solid-state polymer electrolytes for the stable long-term operation of both anode and cathode.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":null,"pages":null},"PeriodicalIF":13.0000,"publicationDate":"2022-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"14","resultStr":"{\"title\":\"A Multifunctional Silicon-Doped Polyether Network for Double Stable Interfaces in Quasi-Solid-State Lithium Metal Batteries\",\"authors\":\"Qi Zhang, Xiao Liu, Hao Li, Zhijie Guo, Tengfei Bian, Xuebing Zhu, Niannian Zhan, Yong Zhao\",\"doi\":\"10.1002/smll.202106395\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Polymer-based quasi-solid-state electrolyte (QSE) is an effective means to solve the safety problem of lithium (Li) metal batteries, and stable solid-electrolyte-interface (SEI) layers between electrolyte and anode/cathode are highly required for their long-term stability. Herein, it is demonstrated that a silicon-doped polyether functions as a multifunctional unit, which can induce the formation of stable and robust SEI layers with rich Li<sub>x</sub>SiO<sub>y</sub> on both the surfaces of cathode and anode. It simultaneously solves the compatibility of electrolyte and electrodes in the quasi-solid-state Li-metal battery. Moreover, the robust polymer skeleton with a cross-linked network is beneficial to inhibit liquid volatilization and improve battery safety. The assembled Li|QSE|LiFePO<sub>4</sub> batteries show a capacity retention rate as high as 97.5% after 400 cycles at 1 C (30 °C), and reach 78.1% after 1000 cycles. Furthermore, there is almost no attenuation of reversible capacity after 100 cycles for the assembled Li|QSE|LiNi<sub>0.8</sub>Mn<sub>0.1</sub>Co<sub>0.1</sub>O<sub>2</sub> batteries. The concept of silicon-doped polymer with a crosslinking structure provides an important strategy for designing solid-state or quasi-solid-state polymer electrolytes for the stable long-term operation of both anode and cathode.</p>\",\"PeriodicalId\":228,\"journal\":{\"name\":\"Small\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":13.0000,\"publicationDate\":\"2022-01-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"14\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Small\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/smll.202106395\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Small","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/smll.202106395","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A Multifunctional Silicon-Doped Polyether Network for Double Stable Interfaces in Quasi-Solid-State Lithium Metal Batteries
Polymer-based quasi-solid-state electrolyte (QSE) is an effective means to solve the safety problem of lithium (Li) metal batteries, and stable solid-electrolyte-interface (SEI) layers between electrolyte and anode/cathode are highly required for their long-term stability. Herein, it is demonstrated that a silicon-doped polyether functions as a multifunctional unit, which can induce the formation of stable and robust SEI layers with rich LixSiOy on both the surfaces of cathode and anode. It simultaneously solves the compatibility of electrolyte and electrodes in the quasi-solid-state Li-metal battery. Moreover, the robust polymer skeleton with a cross-linked network is beneficial to inhibit liquid volatilization and improve battery safety. The assembled Li|QSE|LiFePO4 batteries show a capacity retention rate as high as 97.5% after 400 cycles at 1 C (30 °C), and reach 78.1% after 1000 cycles. Furthermore, there is almost no attenuation of reversible capacity after 100 cycles for the assembled Li|QSE|LiNi0.8Mn0.1Co0.1O2 batteries. The concept of silicon-doped polymer with a crosslinking structure provides an important strategy for designing solid-state or quasi-solid-state polymer electrolytes for the stable long-term operation of both anode and cathode.
期刊介绍:
Small serves as an exceptional platform for both experimental and theoretical studies in fundamental and applied interdisciplinary research at the nano- and microscale. The journal offers a compelling mix of peer-reviewed Research Articles, Reviews, Perspectives, and Comments.
With a remarkable 2022 Journal Impact Factor of 13.3 (Journal Citation Reports from Clarivate Analytics, 2023), Small remains among the top multidisciplinary journals, covering a wide range of topics at the interface of materials science, chemistry, physics, engineering, medicine, and biology.
Small's readership includes biochemists, biologists, biomedical scientists, chemists, engineers, information technologists, materials scientists, physicists, and theoreticians alike.