{"title":"CuO/CuxS复合材料的制备及其热电性能","authors":"Rafiq Mulla, M. K. Rabinal","doi":"10.1007/s40243-021-00189-7","DOIUrl":null,"url":null,"abstract":"<p>Herein, copper oxide/copper sulfide (CuO/Cu<sub>x</sub>S) composites have been prepared by treating CuO with thiourea by an aqueous hydrothermal route and their thermoelectric properties are studied. The electrical conductivity is improved with the increase in thiourea content, as a result, thermoelectric power factor increased from 10<sup>–4</sup> to 10<sup>1</sup>?μW?m<sup>?1</sup>?K<sup>?2</sup>, and thermal conductivity of the CuO is also found to decrease with thiourea treatment. A detailed analysis indicated that these changes are due to the formation of copper sulfide (Cu<sub>x</sub>S) in the CuO compound; a small fraction of electrically good conducting Cu<sub>x</sub>S in the bulk CuO has produced composites with better electrical conductivity. These low-cost and non-toxic materials can be useful in thermoelectric energy conversion applications.</p>","PeriodicalId":692,"journal":{"name":"Materials for Renewable and Sustainable Energy","volume":null,"pages":null},"PeriodicalIF":3.6000,"publicationDate":"2021-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s40243-021-00189-7","citationCount":"6","resultStr":"{\"title\":\"CuO/CuxS composites fabrication and their thermoelectric properties\",\"authors\":\"Rafiq Mulla, M. K. Rabinal\",\"doi\":\"10.1007/s40243-021-00189-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Herein, copper oxide/copper sulfide (CuO/Cu<sub>x</sub>S) composites have been prepared by treating CuO with thiourea by an aqueous hydrothermal route and their thermoelectric properties are studied. The electrical conductivity is improved with the increase in thiourea content, as a result, thermoelectric power factor increased from 10<sup>–4</sup> to 10<sup>1</sup>?μW?m<sup>?1</sup>?K<sup>?2</sup>, and thermal conductivity of the CuO is also found to decrease with thiourea treatment. A detailed analysis indicated that these changes are due to the formation of copper sulfide (Cu<sub>x</sub>S) in the CuO compound; a small fraction of electrically good conducting Cu<sub>x</sub>S in the bulk CuO has produced composites with better electrical conductivity. These low-cost and non-toxic materials can be useful in thermoelectric energy conversion applications.</p>\",\"PeriodicalId\":692,\"journal\":{\"name\":\"Materials for Renewable and Sustainable Energy\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2021-01-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1007/s40243-021-00189-7\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials for Renewable and Sustainable Energy\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s40243-021-00189-7\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials for Renewable and Sustainable Energy","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1007/s40243-021-00189-7","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
CuO/CuxS composites fabrication and their thermoelectric properties
Herein, copper oxide/copper sulfide (CuO/CuxS) composites have been prepared by treating CuO with thiourea by an aqueous hydrothermal route and their thermoelectric properties are studied. The electrical conductivity is improved with the increase in thiourea content, as a result, thermoelectric power factor increased from 10–4 to 101?μW?m?1?K?2, and thermal conductivity of the CuO is also found to decrease with thiourea treatment. A detailed analysis indicated that these changes are due to the formation of copper sulfide (CuxS) in the CuO compound; a small fraction of electrically good conducting CuxS in the bulk CuO has produced composites with better electrical conductivity. These low-cost and non-toxic materials can be useful in thermoelectric energy conversion applications.
期刊介绍：
Energy is the single most valuable resource for human activity and the basis for all human progress. Materials play a key role in enabling technologies that can offer promising solutions to achieve renewable and sustainable energy pathways for the future.
Materials for Renewable and Sustainable Energy has been established to be the world''s foremost interdisciplinary forum for publication of research on all aspects of the study of materials for the deployment of renewable and sustainable energy technologies. The journal covers experimental and theoretical aspects of materials and prototype devices for sustainable energy conversion, storage, and saving, together with materials needed for renewable fuel production. It publishes reviews, original research articles, rapid communications, and perspectives. All manuscripts are peer-reviewed for scientific quality.
Topics include:
1. MATERIALS for renewable energy storage and conversion: Batteries, Supercapacitors, Fuel cells, Hydrogen storage, and Photovoltaics and solar cells.
2. MATERIALS for renewable and sustainable fuel production: Hydrogen production and fuel generation from renewables (catalysis), Solar-driven reactions to hydrogen and fuels from renewables (photocatalysis), Biofuels, and Carbon dioxide sequestration and conversion.
3. MATERIALS for energy saving: Thermoelectrics, Novel illumination sources for efficient lighting, and Energy saving in buildings.
4. MATERIALS modeling and theoretical aspects.
5. Advanced characterization techniques of MATERIALS
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