Shu Yang, Wenxin Dong, Li Zhang, Kaihua He, Wei Dai, Chen Lu
{"title":"极端条件下Mg2SiO4橄榄石及其多晶的晶格热导率","authors":"Shu Yang, Wenxin Dong, Li Zhang, Kaihua He, Wei Dai, Chen Lu","doi":"10.1007/s00269-023-01240-x","DOIUrl":null,"url":null,"abstract":"<div><p>The thermal transport properties of minerals at high temperature and high pressure are important for understanding the internal evolution and dynamic processes of the Earth. Here, we carry out a detailed study on the lattice thermal conductivities (<span>\\({\\kappa }_\\text {latt}\\)</span>) of <span>\\(\\text {Mg}_2\\text {SiO}_4\\)</span> under upper mantle and transition zone conditions by anharmonic lattice dynamics method. The calculations show that the <span>\\({\\kappa }_\\text {latt}\\)</span> of <span>\\(\\text {Mg}_2\\text {SiO}_4\\)</span> increase with the phase transitions, which agree with the previous measurements and are attributed to the increase of lifetime and group velocity under extreme conditions. The <span>\\({\\kappa }_\\text {latt}\\)</span> of <span>\\(\\text {Mg}_2\\text {SiO}_4\\)</span> along the geotherm shows a 64<span>\\(\\%\\)</span> jump at 410 <span>\\({\\textrm{km}}\\)</span> and 71<span>\\(\\%\\)</span> jump at 520 <span>\\(\\textrm{km}\\)</span>. The anisotropy in the <span>\\({\\kappa }_\\text {latt}\\)</span> of olivine and wadsleyite decreases with increasing pressure. The present findings offer a fundamental knowledge of the <span>\\({\\kappa }_\\text {latt}\\)</span> of <span>\\(\\text {Mg}_2\\text {SiO}_4\\)</span> under extreme conditions, which are crucially important for understanding the thermal transport processes in the Earth.</p></div>","PeriodicalId":20132,"journal":{"name":"Physics and Chemistry of Minerals","volume":null,"pages":null},"PeriodicalIF":1.2000,"publicationDate":"2023-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Lattice thermal conductivity of Mg2SiO4 olivine and its polymorphs under extreme conditions\",\"authors\":\"Shu Yang, Wenxin Dong, Li Zhang, Kaihua He, Wei Dai, Chen Lu\",\"doi\":\"10.1007/s00269-023-01240-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The thermal transport properties of minerals at high temperature and high pressure are important for understanding the internal evolution and dynamic processes of the Earth. Here, we carry out a detailed study on the lattice thermal conductivities (<span>\\\\({\\\\kappa }_\\\\text {latt}\\\\)</span>) of <span>\\\\(\\\\text {Mg}_2\\\\text {SiO}_4\\\\)</span> under upper mantle and transition zone conditions by anharmonic lattice dynamics method. The calculations show that the <span>\\\\({\\\\kappa }_\\\\text {latt}\\\\)</span> of <span>\\\\(\\\\text {Mg}_2\\\\text {SiO}_4\\\\)</span> increase with the phase transitions, which agree with the previous measurements and are attributed to the increase of lifetime and group velocity under extreme conditions. The <span>\\\\({\\\\kappa }_\\\\text {latt}\\\\)</span> of <span>\\\\(\\\\text {Mg}_2\\\\text {SiO}_4\\\\)</span> along the geotherm shows a 64<span>\\\\(\\\\%\\\\)</span> jump at 410 <span>\\\\({\\\\textrm{km}}\\\\)</span> and 71<span>\\\\(\\\\%\\\\)</span> jump at 520 <span>\\\\(\\\\textrm{km}\\\\)</span>. The anisotropy in the <span>\\\\({\\\\kappa }_\\\\text {latt}\\\\)</span> of olivine and wadsleyite decreases with increasing pressure. The present findings offer a fundamental knowledge of the <span>\\\\({\\\\kappa }_\\\\text {latt}\\\\)</span> of <span>\\\\(\\\\text {Mg}_2\\\\text {SiO}_4\\\\)</span> under extreme conditions, which are crucially important for understanding the thermal transport processes in the Earth.</p></div>\",\"PeriodicalId\":20132,\"journal\":{\"name\":\"Physics and Chemistry of Minerals\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2023-04-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physics and Chemistry of Minerals\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00269-023-01240-x\",\"RegionNum\":4,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physics and Chemistry of Minerals","FirstCategoryId":"89","ListUrlMain":"https://link.springer.com/article/10.1007/s00269-023-01240-x","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Lattice thermal conductivity of Mg2SiO4 olivine and its polymorphs under extreme conditions
The thermal transport properties of minerals at high temperature and high pressure are important for understanding the internal evolution and dynamic processes of the Earth. Here, we carry out a detailed study on the lattice thermal conductivities (\({\kappa }_\text {latt}\)) of \(\text {Mg}_2\text {SiO}_4\) under upper mantle and transition zone conditions by anharmonic lattice dynamics method. The calculations show that the \({\kappa }_\text {latt}\) of \(\text {Mg}_2\text {SiO}_4\) increase with the phase transitions, which agree with the previous measurements and are attributed to the increase of lifetime and group velocity under extreme conditions. The \({\kappa }_\text {latt}\) of \(\text {Mg}_2\text {SiO}_4\) along the geotherm shows a 64\(\%\) jump at 410 \({\textrm{km}}\) and 71\(\%\) jump at 520 \(\textrm{km}\). The anisotropy in the \({\kappa }_\text {latt}\) of olivine and wadsleyite decreases with increasing pressure. The present findings offer a fundamental knowledge of the \({\kappa }_\text {latt}\) of \(\text {Mg}_2\text {SiO}_4\) under extreme conditions, which are crucially important for understanding the thermal transport processes in the Earth.
期刊介绍:
Physics and Chemistry of Minerals is an international journal devoted to publishing articles and short communications of physical or chemical studies on minerals or solids related to minerals. The aim of the journal is to support competent interdisciplinary work in mineralogy and physics or chemistry. Particular emphasis is placed on applications of modern techniques or new theories and models to interpret atomic structures and physical or chemical properties of minerals. Some subjects of interest are:
-Relationships between atomic structure and crystalline state (structures of various states, crystal energies, crystal growth, thermodynamic studies, phase transformations, solid solution, exsolution phenomena, etc.)
-General solid state spectroscopy (ultraviolet, visible, infrared, Raman, ESCA, luminescence, X-ray, electron paramagnetic resonance, nuclear magnetic resonance, gamma ray resonance, etc.)
-Experimental and theoretical analysis of chemical bonding in minerals (application of crystal field, molecular orbital, band theories, etc.)
-Physical properties (magnetic, mechanical, electric, optical, thermodynamic, etc.)
-Relations between thermal expansion, compressibility, elastic constants, and fundamental properties of atomic structure, particularly as applied to geophysical problems
-Electron microscopy in support of physical and chemical studies
-Computational methods in the study of the structure and properties of minerals
-Mineral surfaces (experimental methods, structure and properties)