装配压力对质子交换膜燃料电池性能的影响

Zhuo Zhang, Wen-Quan Tao
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引用次数: 1

摘要

组装力是质子交换膜燃料电池(PEMFC)堆积过程中的关键因素,对燃料电池的流体流动、传质、水热管理等产生重要影响,进而影响燃料电池的性能。本研究从最易变形的气体扩散层(GDL)出发,结合有限元分析和计算流体动力学方法,分析了装配力对单通道PEMFC的影响。创造性地将微观分析得到的非线性应力-应变曲线引入二维压缩模型。通过微观模拟得到了三维模型中的气体扩散系数。模拟得到压缩GDL的有效氧扩散系数约为Bruggemann估定值的0.86倍。当忽略接触电阻时,在1.7 A·cm−2时,2.5 MPa的输出电压比0.5 MPa时降低了约15.4%。考虑接触电阻后,组装压力对电池性能的影响(V-I曲线)有质的不同。在1.7 A cm−2时,2.5 MPa的压降比1.4 MPa的压降高20%。肋下孔隙度和渗透率较低的区域,氧气很难流入。结果表明,随着组装力的增大,液态水和膜含水量均增加。分析了装配力对温度的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of assembly pressure on the performance of proton exchange membrane fuel cell

The assembly force is a crucial factor in the process of proton exchange membrane fuel cell (PEMFC) stacking, and has significant effects on the fluid flow, mass transfer, and water and thermal management, which affect the fuel cell performance. In this study, from the most deformable component, the gas diffusion layer (GDL), combining with a finite-element analysis, and computational fluid dynamic method, the impact of the assembly force on a single-channel PEMFC is analyzed. A nonlinear stress–strain curve obtained from a microanalysis is creatively introduced into the two-dimensional compression model. The gas diffusion coefficient in the three-dimensional model is also obtained from the microscopic simulation. The simulated effective oxygen diffusion coefficient of the compressed GDL is approximately 0.86 times the Bruggemann estimated value. When the contact resistance is ignored, the output voltage at 2.5 MPa is decreased by approximately 15.4% at 1.7 A·cm−2 compared with that at 0.5 MPa. After the contact resistance is considered, the effects of the assembly pressure on the cell performance (V–I curve) are qualitatively different. The pressure drop of the 2.5 MPa case is 20% higher than that of the 1.4 MPa case at 1.7 A cm−2. O2 is hard to flow into the region under the rib where the porosity and permeability are lower. The results indicate that both liquid water and membrane water contents increase when the assembly force increases. The effect of the assembly force on the temperature is also analyzed.

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