新型ZnO/活性炭复合材料阴离子染料的合成、表征及光催化降解研究

A. Machrouhi , H. Khiar , A. Elhalil , M. Sadiq , M. Abdennouri , N. Barka
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引用次数: 0

摘要

氧化锌/活性炭(ZnO/ACTTS)复合材料对从水溶液中去除甲基橙(MO)染料具有良好的光催化性能。本研究采用磷酸化学活化法制备活性炭,然后通过水热技术在不同ZnO含量(15%、30%、50%和75%)下合成ZnO/ACTTS复合材料。利用XRD、FTIR和SEM-EDX对制备的复合材料进行了表征。研究了光催化降解水溶液中MO染料的催化剂。研究了氧化锌含量、溶液pH值和催化剂用量对催化剂性能的影响。实验结果表明,ZnO/ACTTS(75%)复合材料在最佳催化剂用量为0.5g/L的酸性pH条件下表现出良好的活性。光降解动力学遵循准二级动力学。ZnO/ACTTS复合材料将成为一种催化剂,在水介质中降解纺织工业中的各种染料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis, characterization, and photocatalytic degradation of anionic dyes using a novel ZnO/activated carbon composite

Zinc oxide/activated carbon from Thapsia transtagana stems (ZnO/ACTTS) composite demonstrated good photocatalytic properties for removing methyl orange (MO) dye from aqueous solution. This study utilized the chemical activation method using phosphoric acid to prepare activated carbon, which was then used to synthesize the ZnO/ACTTS composites by the hydrothermal technique at different percentages of the amount of ZnO (15, 30, 50 and 75 %). XRD, FTIR, and SEM-EDX were used to characterize the produced composite materials. The photocatalytic degradation of the catalysts was investigated for the degradation of MO dye from aqueous solution. The effects of zinc oxide content, pH of solution, and catalyst dosage were studied. Experimental results indicate that the ZnO/ACTTS (75 %) composite with exhibited good activity under acid pH conditions with an optimal catalyst dosage of 0.5 g/L. Photodegradation kinetics followed a pseudo-second order kinetics. ZnO/ACTTS composite will be a catalyst to degrade a wide range of dyes from the textile industry in the aquatic medium.

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