新的2-氯-1,3,2-二氮磷-4- 1 -2-氧化物衍生物的绿色合成方法

IF 1.4 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2023-01-01 DOI:10.1080/10426507.2023.2184362

Samar Kherfani , Raoudha Abderrahim

{"title":"新的2-氯-1,3,2-二氮磷-4- 1 -2-氧化物衍生物的绿色合成方法","authors":"Samar Kherfani , Raoudha Abderrahim","doi":"10.1080/10426507.2023.2184362","DOIUrl":null,"url":null,"abstract":"<div><p>In this work, we describe a novel, easy and green method for the synthesis of diazaphosphinine derivatives. The new diazaphosphinines were prepared by condensation of phosphorus oxychloride with the corresponding benzamides under reflux in acetone with moderate to good yields. The structures of the new compounds were confirmed on the basis of their infrared and nuclear magnetic resonance spectral data (<sup>1</sup>H, <sup>13</sup>C, and <sup>31</sup>P), MS, and elemental analysis.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A greener approach of synthesis of new 2-chloro-1,3,2-diazaphosphinin-4-one-2-oxide derivatives\",\"authors\":\"Samar Kherfani , Raoudha Abderrahim\",\"doi\":\"10.1080/10426507.2023.2184362\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this work, we describe a novel, easy and green method for the synthesis of diazaphosphinine derivatives. The new diazaphosphinines were prepared by condensation of phosphorus oxychloride with the corresponding benzamides under reflux in acetone with moderate to good yields. The structures of the new compounds were confirmed on the basis of their infrared and nuclear magnetic resonance spectral data (<sup>1</sup>H, <sup>13</sup>C, and <sup>31</sup>P), MS, and elemental analysis.</p></div>\",\"PeriodicalId\":20056,\"journal\":{\"name\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1042650723000266\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus, Sulfur, and Silicon and the Related Elements","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650723000266","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

在本工作中，我们描述了一种新的、简单的、绿色的合成二氮膦衍生物的方法。新的二氮杂膦是由氯氧化磷和相应的苯甲酰胺在丙酮中回流缩合制备的，产率适中至良好。根据它们的红外和核磁共振光谱数据（1H、13C和31P）、MS和元素分析，确认了新化合物的结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

A greener approach of synthesis of new 2-chloro-1,3,2-diazaphosphinin-4-one-2-oxide derivatives

In this work, we describe a novel, easy and green method for the synthesis of diazaphosphinine derivatives. The new diazaphosphinines were prepared by condensation of phosphorus oxychloride with the corresponding benzamides under reflux in acetone with moderate to good yields. The structures of the new compounds were confirmed on the basis of their infrared and nuclear magnetic resonance spectral data (¹H, ¹³C, and ³¹P), MS, and elemental analysis.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Phosphorus, Sulfur, and Silicon and the Related Elements 化学-无机化学与核化学

CiteScore

2.60

自引率

7.70%

发文量

103

审稿时长

2.1 months

期刊介绍： Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.