Shuping Ji , Yu Dong , Puyan Hao, Mengzhen Jia, Rui Zhu, Yiming Zhang, Xiaoqi Zhao, Lei Zhao
{"title":"对硝基苯甲酸自组装Eu(III)配位聚合物的晶体结构和热增强光致发光","authors":"Shuping Ji , Yu Dong , Puyan Hao, Mengzhen Jia, Rui Zhu, Yiming Zhang, Xiaoqi Zhao, Lei Zhao","doi":"10.1016/j.omx.2023.100266","DOIUrl":null,"url":null,"abstract":"<div><p>Luminescent thermal quenching is a very troublesome thing for the practical application of luminescent materials, but also is a very common phenomenon. In theory, artificially reducing the number of quenching group around the luminescent lanthanide ion can effectively enhance the luminescence of lanthanide luminescent materials. In this paper, {[Eu<sub>2</sub>(NBA)<sub>6</sub>(H<sub>2</sub>O)<sub>4</sub>]∙H<sub>2</sub>O}<sub>n</sub> [Eu-NBA, NBA = p-nitrobenzoic acid] coordination polymers containing abundant coordination and interstitial water molecules were synthesized <em>via</em> hydrothermal methods. The chemical composition, crystal structures, and thermal stability of Eu-NBA coordination polymers were systemically investigated by Frontier-transfer infrared (FTIR) spectra, single-crystal X-ray diffraction and thermogravimetric analysis. X-ray diffraction analysis results revealed that Eu-NBA coordination polymers were crystallized into one-dimensional (1D) chain structures, where the adjacent Eu<sup>3+</sup> ions were linked together by bidentate and/or tetradentate bridging carboxylate groups of the NBA ligands. The temperature-dependent photoluminescence spectra revealed that the shape and intensity of the luminescence spectra strongly depended on the coordination environment around Eu<sup>3+</sup>, and significant luminescent thermal enhancement was observed. These experimental results provided useful theoretical support for further understanding of the luminescence enhancement mechanism of lanthanide coordination polymers.</p></div>","PeriodicalId":52192,"journal":{"name":"Optical Materials: X","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Crystal structure and thermally enhanced photoluminescence in Eu(III) coordination polymers self-assembled from p-nitrobenzoic acid\",\"authors\":\"Shuping Ji , Yu Dong , Puyan Hao, Mengzhen Jia, Rui Zhu, Yiming Zhang, Xiaoqi Zhao, Lei Zhao\",\"doi\":\"10.1016/j.omx.2023.100266\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Luminescent thermal quenching is a very troublesome thing for the practical application of luminescent materials, but also is a very common phenomenon. In theory, artificially reducing the number of quenching group around the luminescent lanthanide ion can effectively enhance the luminescence of lanthanide luminescent materials. In this paper, {[Eu<sub>2</sub>(NBA)<sub>6</sub>(H<sub>2</sub>O)<sub>4</sub>]∙H<sub>2</sub>O}<sub>n</sub> [Eu-NBA, NBA = p-nitrobenzoic acid] coordination polymers containing abundant coordination and interstitial water molecules were synthesized <em>via</em> hydrothermal methods. The chemical composition, crystal structures, and thermal stability of Eu-NBA coordination polymers were systemically investigated by Frontier-transfer infrared (FTIR) spectra, single-crystal X-ray diffraction and thermogravimetric analysis. X-ray diffraction analysis results revealed that Eu-NBA coordination polymers were crystallized into one-dimensional (1D) chain structures, where the adjacent Eu<sup>3+</sup> ions were linked together by bidentate and/or tetradentate bridging carboxylate groups of the NBA ligands. The temperature-dependent photoluminescence spectra revealed that the shape and intensity of the luminescence spectra strongly depended on the coordination environment around Eu<sup>3+</sup>, and significant luminescent thermal enhancement was observed. These experimental results provided useful theoretical support for further understanding of the luminescence enhancement mechanism of lanthanide coordination polymers.</p></div>\",\"PeriodicalId\":52192,\"journal\":{\"name\":\"Optical Materials: X\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-09-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Optical Materials: X\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2590147823000402\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optical Materials: X","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2590147823000402","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Engineering","Score":null,"Total":0}
Crystal structure and thermally enhanced photoluminescence in Eu(III) coordination polymers self-assembled from p-nitrobenzoic acid
Luminescent thermal quenching is a very troublesome thing for the practical application of luminescent materials, but also is a very common phenomenon. In theory, artificially reducing the number of quenching group around the luminescent lanthanide ion can effectively enhance the luminescence of lanthanide luminescent materials. In this paper, {[Eu2(NBA)6(H2O)4]∙H2O}n [Eu-NBA, NBA = p-nitrobenzoic acid] coordination polymers containing abundant coordination and interstitial water molecules were synthesized via hydrothermal methods. The chemical composition, crystal structures, and thermal stability of Eu-NBA coordination polymers were systemically investigated by Frontier-transfer infrared (FTIR) spectra, single-crystal X-ray diffraction and thermogravimetric analysis. X-ray diffraction analysis results revealed that Eu-NBA coordination polymers were crystallized into one-dimensional (1D) chain structures, where the adjacent Eu3+ ions were linked together by bidentate and/or tetradentate bridging carboxylate groups of the NBA ligands. The temperature-dependent photoluminescence spectra revealed that the shape and intensity of the luminescence spectra strongly depended on the coordination environment around Eu3+, and significant luminescent thermal enhancement was observed. These experimental results provided useful theoretical support for further understanding of the luminescence enhancement mechanism of lanthanide coordination polymers.