Ahmed Hjazi , Yasir Qasim Almajidi , Wesam R. Kadhum , Mohammed Aly , Jitendra Malviya , Mohammed N. Fenjan , Ahmed Alawadi , Ali Alsaalamy , Awadhesh Chandramauli , Leila Baharinikoo
{"title":"中心复合设计优化磁性纳米复合材料对水样中磺胺类抗生素的去除效果","authors":"Ahmed Hjazi , Yasir Qasim Almajidi , Wesam R. Kadhum , Mohammed Aly , Jitendra Malviya , Mohammed N. Fenjan , Ahmed Alawadi , Ali Alsaalamy , Awadhesh Chandramauli , Leila Baharinikoo","doi":"10.1016/j.wri.2023.100229","DOIUrl":null,"url":null,"abstract":"<div><p>The present study aimed to remove sulfonamide antibiotics from water samples using magnetic Fe<sub>3</sub>O<sub>4</sub>-bentonite nanocomposite (Fe<sub>3</sub>O<sub>4</sub>-Bt) as an adsorbent. The adsorbent has a surface area of 74.27 m<sup>2</sup> g<sup>-1</sup>, a pore size of 87.53 nm, and a pore volume of 0.146 cm<sup>3</sup> g<sup>-1</sup>. A central composite design (CCD) matrix was employed to model and optimize the process. The optimal conditions for removing sulfonamide antibiotics were determined using Fe<sub>3</sub>O<sub>4</sub>-Bt adsorbent at an antibiotic concentration of 20 mg L<sup>-1</sup>, the amount of nanoparticles of 0.23 g, pH of 6, and ultrasonication time of 17 min. The reusability study of the Fe<sub>3</sub>O<sub>4</sub>-Bt adsorbent showed that the Fe<sub>3</sub>O<sub>4</sub>-Bt could be used five times in adsorption/desorption processes. Also, applying the Fe<sub>3</sub>O<sub>4</sub>-Bt adsorbent on real samples revealed that Fe<sub>3</sub>O<sub>4</sub>-Bt adsorbent could remove sulfonamide antibiotics in the range of 86.85–97.47% with RSD (n = 5) < 4.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"30 ","pages":"Article 100229"},"PeriodicalIF":4.5000,"publicationDate":"2023-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Optimization of removal of sulfonamide antibiotics by magnetic nanocomposite from water samples using central composite design\",\"authors\":\"Ahmed Hjazi , Yasir Qasim Almajidi , Wesam R. Kadhum , Mohammed Aly , Jitendra Malviya , Mohammed N. Fenjan , Ahmed Alawadi , Ali Alsaalamy , Awadhesh Chandramauli , Leila Baharinikoo\",\"doi\":\"10.1016/j.wri.2023.100229\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The present study aimed to remove sulfonamide antibiotics from water samples using magnetic Fe<sub>3</sub>O<sub>4</sub>-bentonite nanocomposite (Fe<sub>3</sub>O<sub>4</sub>-Bt) as an adsorbent. The adsorbent has a surface area of 74.27 m<sup>2</sup> g<sup>-1</sup>, a pore size of 87.53 nm, and a pore volume of 0.146 cm<sup>3</sup> g<sup>-1</sup>. A central composite design (CCD) matrix was employed to model and optimize the process. The optimal conditions for removing sulfonamide antibiotics were determined using Fe<sub>3</sub>O<sub>4</sub>-Bt adsorbent at an antibiotic concentration of 20 mg L<sup>-1</sup>, the amount of nanoparticles of 0.23 g, pH of 6, and ultrasonication time of 17 min. The reusability study of the Fe<sub>3</sub>O<sub>4</sub>-Bt adsorbent showed that the Fe<sub>3</sub>O<sub>4</sub>-Bt could be used five times in adsorption/desorption processes. Also, applying the Fe<sub>3</sub>O<sub>4</sub>-Bt adsorbent on real samples revealed that Fe<sub>3</sub>O<sub>4</sub>-Bt adsorbent could remove sulfonamide antibiotics in the range of 86.85–97.47% with RSD (n = 5) < 4.</p></div>\",\"PeriodicalId\":23714,\"journal\":{\"name\":\"Water Resources and Industry\",\"volume\":\"30 \",\"pages\":\"Article 100229\"},\"PeriodicalIF\":4.5000,\"publicationDate\":\"2023-10-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Water Resources and Industry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S221237172300029X\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"WATER RESOURCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water Resources and Industry","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S221237172300029X","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"WATER RESOURCES","Score":null,"Total":0}
Optimization of removal of sulfonamide antibiotics by magnetic nanocomposite from water samples using central composite design
The present study aimed to remove sulfonamide antibiotics from water samples using magnetic Fe3O4-bentonite nanocomposite (Fe3O4-Bt) as an adsorbent. The adsorbent has a surface area of 74.27 m2 g-1, a pore size of 87.53 nm, and a pore volume of 0.146 cm3 g-1. A central composite design (CCD) matrix was employed to model and optimize the process. The optimal conditions for removing sulfonamide antibiotics were determined using Fe3O4-Bt adsorbent at an antibiotic concentration of 20 mg L-1, the amount of nanoparticles of 0.23 g, pH of 6, and ultrasonication time of 17 min. The reusability study of the Fe3O4-Bt adsorbent showed that the Fe3O4-Bt could be used five times in adsorption/desorption processes. Also, applying the Fe3O4-Bt adsorbent on real samples revealed that Fe3O4-Bt adsorbent could remove sulfonamide antibiotics in the range of 86.85–97.47% with RSD (n = 5) < 4.
期刊介绍:
Water Resources and Industry moves research to innovation by focusing on the role industry plays in the exploitation, management and treatment of water resources. Different industries use radically different water resources in their production processes, while they produce, treat and dispose a wide variety of wastewater qualities. Depending on the geographical location of the facilities, the impact on the local resources will vary, pre-empting the applicability of one single approach. The aims and scope of the journal include: -Industrial water footprint assessment - an evaluation of tools and methodologies -What constitutes good corporate governance and policy and how to evaluate water-related risk -What constitutes good stakeholder collaboration and engagement -New technologies enabling companies to better manage water resources -Integration of water and energy and of water treatment and production processes in industry