{"title":"当过渡金属催化的C–H活化满足烯化学时","authors":"Shu-Meng Deng, Yu-Xuan Zhao, Chengming Wang","doi":"10.1016/j.tchem.2023.100049","DOIUrl":null,"url":null,"abstract":"<div><p>Transition-metal-catalyzed allenes-involved C–H functionalizations demonstrate unique selectivity and undergo exceptional pathways due to the existence of elusive orthogonal cumulative C<img>C<img>C bonds. As a result, it allows for a diverse array of C–H activation reactions, such as allylation, alkenylation, allenylation, dienylation, propargylation, and annulation. In this review, we comprehensively summarize the noteworthy aspects of transition-metal-catalyzed C–H functionalizations involving variously substituted allenes.</p></div>","PeriodicalId":74918,"journal":{"name":"Tetrahedron chem","volume":"8 ","pages":"Article 100049"},"PeriodicalIF":0.0000,"publicationDate":"2023-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"When transition-metal-catalyzed C–H activation meets allene chemistry\",\"authors\":\"Shu-Meng Deng, Yu-Xuan Zhao, Chengming Wang\",\"doi\":\"10.1016/j.tchem.2023.100049\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Transition-metal-catalyzed allenes-involved C–H functionalizations demonstrate unique selectivity and undergo exceptional pathways due to the existence of elusive orthogonal cumulative C<img>C<img>C bonds. As a result, it allows for a diverse array of C–H activation reactions, such as allylation, alkenylation, allenylation, dienylation, propargylation, and annulation. In this review, we comprehensively summarize the noteworthy aspects of transition-metal-catalyzed C–H functionalizations involving variously substituted allenes.</p></div>\",\"PeriodicalId\":74918,\"journal\":{\"name\":\"Tetrahedron chem\",\"volume\":\"8 \",\"pages\":\"Article 100049\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-09-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tetrahedron chem\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666951X23000153\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron chem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666951X23000153","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
When transition-metal-catalyzed C–H activation meets allene chemistry
Transition-metal-catalyzed allenes-involved C–H functionalizations demonstrate unique selectivity and undergo exceptional pathways due to the existence of elusive orthogonal cumulative CCC bonds. As a result, it allows for a diverse array of C–H activation reactions, such as allylation, alkenylation, allenylation, dienylation, propargylation, and annulation. In this review, we comprehensively summarize the noteworthy aspects of transition-metal-catalyzed C–H functionalizations involving variously substituted allenes.
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