{"title":"磺酰肼在水中的有机无溶剂合成","authors":"Shizuki Noda, Shinji Tanimori","doi":"10.1016/j.tgchem.2022.100001","DOIUrl":null,"url":null,"abstract":"<div><p>An organic solvent-free synthesis of sulfonyl hydrazides has been achieved in water. The reactions of equimolar amount of sulfonyl chlorides and hydrazines afforded a series of substituted sulfonyl hydrazides at 60 °C for 1 h in water as a solvent in the presence of triethylamine when hydrazines are hydrochlorides. Moderate to good yields were observed for this transformation by the simple operation (46–93%). The reaction of amines, anilines, alcohol, and phenol have also been investigated in water.</p></div>","PeriodicalId":101215,"journal":{"name":"Tetrahedron Green Chem","volume":"1 ","pages":"Article 100001"},"PeriodicalIF":0.0000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Organic solvent-free synthesis of sulfonyl hydrazides in water\",\"authors\":\"Shizuki Noda, Shinji Tanimori\",\"doi\":\"10.1016/j.tgchem.2022.100001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>An organic solvent-free synthesis of sulfonyl hydrazides has been achieved in water. The reactions of equimolar amount of sulfonyl chlorides and hydrazines afforded a series of substituted sulfonyl hydrazides at 60 °C for 1 h in water as a solvent in the presence of triethylamine when hydrazines are hydrochlorides. Moderate to good yields were observed for this transformation by the simple operation (46–93%). The reaction of amines, anilines, alcohol, and phenol have also been investigated in water.</p></div>\",\"PeriodicalId\":101215,\"journal\":{\"name\":\"Tetrahedron Green Chem\",\"volume\":\"1 \",\"pages\":\"Article 100001\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tetrahedron Green Chem\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2773223122000012\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron Green Chem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2773223122000012","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Organic solvent-free synthesis of sulfonyl hydrazides in water
An organic solvent-free synthesis of sulfonyl hydrazides has been achieved in water. The reactions of equimolar amount of sulfonyl chlorides and hydrazines afforded a series of substituted sulfonyl hydrazides at 60 °C for 1 h in water as a solvent in the presence of triethylamine when hydrazines are hydrochlorides. Moderate to good yields were observed for this transformation by the simple operation (46–93%). The reaction of amines, anilines, alcohol, and phenol have also been investigated in water.
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