酸性环境下蜗牛泥对低碳钢暴露表面缓蚀性能的研究

Ifeanyi Emmanuel Chukwunyere , Titus Chinedu Egbosiuba
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引用次数: 1

摘要

金属腐蚀是各个行业的一个主要问题,使用有机材料,特别是植物提取物作为腐蚀抑制剂中有毒化学物质的替代品越来越受到关注。然而,动物产品作为缓蚀剂的潜力尚未得到充分探索。本研究采用重量法和电化学方法,包括开路电位(OCP)、动电位极化(PDP)和电化学阻抗谱(EIS),研究了蜗牛泥(SS)在0.5M H2SO4溶液中对软钢的缓蚀潜力。利用傅立叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)对材料进行了表征。结果表明,蜗牛粘液具有高达92.75%的抑制效率,抑制效率随着温度和浸泡时间的增加而降低,但随着抑制剂浓度的增加而增加。吸附研究表明,蜗牛泥对Langmuir和Temkin吸附等温线表现出强烈的粘附性,表明其在软钢上的自发吸附。抑制机理表现出典型的物理吸附,并遵循一级动力学。EIS分析表明,蜗牛泥是一种电荷转移控制的腐蚀过程,其最高抑制效率为81.74%,而PDP分析显示,蜗牛泥作为一种混合型缓蚀剂,其最高缓蚀效率为81.98%。FTIR揭示了蜗牛泥缓蚀剂表现出的抑制作用的官能团,包括CH、OH、CO-O、CCl和NH。SEM表明,腐蚀的抑制是由于通过吸附过程在样品表面形成了不溶性稳定的保护膜。这些发现表明,蜗牛泥在工业应用中作为合成缓蚀剂的环保替代品具有巨大的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of the corrosion inhibition performance of snail slime on the exposed surface of mild steel in acidic environment

Corrosion of metals is a major issue in various industries and the use of organic materials, especially plant extracts, as alternatives to toxic chemicals in corrosion inhibitors is gaining attention. However, the potential of animal products as corrosion inhibitors has not been fully explored. This study investigates the corrosion inhibiting potential of snail slime (SS) for mild steel in 0.5 M H2SO4 solution using Gravimetric and electrochemical methods, including open circuit potential (OCP), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS). Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) were used for material characterization. The results indicate that snail slime has a high inhibition efficiency of up to 92.75%, with inhibition efficiency decreasing as temperature and immersion time increase but it increased with higher inhibitor concentrations. Adsorption studies showed that snail slime exhibited strong adherence to the Langmuir and Temkin adsorption isotherms, indicating spontaneous adsorption on mild steel. The inhibition mechanism shows typical physical adsorption and follows first-order kinetics. While the EIS analysis indicated a charge transfer-controlled corrosion process with the highest inhibition efficiency of 81.74%, the PDP analysis revealed that snail slime acted as a mixed-type inhibitor with the highest inhibition efficiency of 81.98%. FTIR reveals the functional groups responsible for the inhibition exhibited by snail slime inhibitors, including CH, OH, CO-O, CCl, and NH. SEM shows that the inhibition of corrosion is due to the formation of an insoluble stable protective film on the sample surface by an adsorption process. These findings suggest that snail slime has significant potential as an eco-friendly alternative to synthetic corrosion inhibitors in industrial applications.

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