铁磁状态下f电子系统热性质的研究

Q4 Chemistry
Asit Kumar Shadangi, G. C. Rout
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引用次数: 0

摘要

稀土和锕系化合物在特征低温下表现出异常的物理性质,具有非常高的比热系数和高的有效质量。这里我们考虑了周期Anderson模型,该模型在平均场近似范围内具有排斥电子-电子相互作用,导致系统中的铁磁性。我们利用Zubarev的Green函数技术计算了传导电子和f电子的Green函数,并对铁磁磁化进行了数值计算和自洽计算。根据f电子系统的电子自由能计算出与温度相关的熵、比热系数和电子比热等热性质,并进行了数值计算。比热系数在系统的重费米子状态下显示出高值,其中f电子能级的位置远离费米能级,f和传导电子之间的杂交强度较低。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The study of thermal properties of f-electron systems in the ferromagnetic state
The rare earth and actinide series of compounds display anomalous physical properties below a characteristic low temperature with very high specific heat coefficient and high effective mass. Here we consider the periodic Anderson model with the repulsive electron-electron interaction within mean-field approximation leading to ferromagnetism in the system. We calculate conduction electron as well as f-electron Green's functions by using Zubarev's Green's function technique and calculate ferromagnetic magnetisation numerically and self consistently. The thermal properties like the temperature dependent entropy, specific heat coefficient and electronic specific heat are calculated from the electron free-energy of the f-electron system and are computed numerically. The specific heat coefficient displays high value in heavy fermion state of the system where the position of the f-electron level is away from the Fermi level with the lower strength of hybridisation between f and conduction electrons.
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来源期刊
International Journal of Nano and Biomaterials
International Journal of Nano and Biomaterials Chemistry-Physical and Theoretical Chemistry
CiteScore
1.20
自引率
0.00%
发文量
0
期刊介绍: In recent years, frontiers of research in engineering, science and technology have been driven by developments in nanomaterials, encompassing a diverse range of disciplines such as materials science, biomedical engineering, nanomedicine and biology, manufacturing technology, biotechnology, nanotechnology, and nanoelectronics. IJNBM provides an interdisciplinary vehicle covering these fields. Advanced materials inspired by biological systems and processes are likely to influence the development of novel technologies for a wide variety of applications from vaccines to artificial tissues and organs to quantum computers. Topics covered include Nanostructured materials/surfaces/interfaces Synthesis of nanostructures Biological/biomedical materials Artificial organs/tissues Tissue engineering Bioengineering materials Medical devices Functional/structural nanomaterials Carbon-based materials Nanomaterials characterisation Novel applications of nanomaterials Modelling of behaviour of nanomaterials Nanomaterials for biomedical applications Biological response to nanomaterials.
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