{"title":"微波制备地质样品用质谱同位素稀释法测定铂族元素和铼","authors":"S. V. Palesskiy, I. V. Nikolaeva, O. A. Kozmenko","doi":"10.1134/S0016702923070042","DOIUrl":null,"url":null,"abstract":"<div><div><p><b>Abstract</b>—We report the first results of the application of UltraWAVE reactor-type microwave system for geological sample preparation (<i>T</i> = 250°C and P up to 80 bar) with a mixture of concentrated nitric and hydrochloric acids (3 : 1). Determination of the platinum group elements – Ru, Pd, Ir, Pt (PGE) and Re after acid digestion was carried out by isotope dilution using the high-resolution mass-spectrometer ELEMENT after chromatographic separation of analytes on an AG50Wx8 cation exchange resin. The monoisotopic rhodium was determined with <sup>195</sup>Pt as an internal standard. The achieved detection limits were from 0.003 ng/g (Ir) to 0.09 ng/g (Pt). The correctness of the new procedure was confirmed by the analysis of geological reference samples—GP-13, UB-N, BHVO-2. The proposed procedure significantly accelerates and simplifies the preparation of geological samples for PGE and Re determination compared to the Carius tube technique.</p></div></div>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"61 7","pages":"744 - 749"},"PeriodicalIF":0.7000,"publicationDate":"2023-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microwave Preparation of Geological Samples in UltraWAVE System for the Determination of Platinum Group Elements and Rhenium by Mass-Spectrometric Isotope Dilution\",\"authors\":\"S. V. Palesskiy, I. V. Nikolaeva, O. A. Kozmenko\",\"doi\":\"10.1134/S0016702923070042\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div><p><b>Abstract</b>—We report the first results of the application of UltraWAVE reactor-type microwave system for geological sample preparation (<i>T</i> = 250°C and P up to 80 bar) with a mixture of concentrated nitric and hydrochloric acids (3 : 1). Determination of the platinum group elements – Ru, Pd, Ir, Pt (PGE) and Re after acid digestion was carried out by isotope dilution using the high-resolution mass-spectrometer ELEMENT after chromatographic separation of analytes on an AG50Wx8 cation exchange resin. The monoisotopic rhodium was determined with <sup>195</sup>Pt as an internal standard. The achieved detection limits were from 0.003 ng/g (Ir) to 0.09 ng/g (Pt). The correctness of the new procedure was confirmed by the analysis of geological reference samples—GP-13, UB-N, BHVO-2. The proposed procedure significantly accelerates and simplifies the preparation of geological samples for PGE and Re determination compared to the Carius tube technique.</p></div></div>\",\"PeriodicalId\":12781,\"journal\":{\"name\":\"Geochemistry International\",\"volume\":\"61 7\",\"pages\":\"744 - 749\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2023-07-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Geochemistry International\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0016702923070042\",\"RegionNum\":4,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Geochemistry International","FirstCategoryId":"89","ListUrlMain":"https://link.springer.com/article/10.1134/S0016702923070042","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Microwave Preparation of Geological Samples in UltraWAVE System for the Determination of Platinum Group Elements and Rhenium by Mass-Spectrometric Isotope Dilution
Abstract—We report the first results of the application of UltraWAVE reactor-type microwave system for geological sample preparation (T = 250°C and P up to 80 bar) with a mixture of concentrated nitric and hydrochloric acids (3 : 1). Determination of the platinum group elements – Ru, Pd, Ir, Pt (PGE) and Re after acid digestion was carried out by isotope dilution using the high-resolution mass-spectrometer ELEMENT after chromatographic separation of analytes on an AG50Wx8 cation exchange resin. The monoisotopic rhodium was determined with 195Pt as an internal standard. The achieved detection limits were from 0.003 ng/g (Ir) to 0.09 ng/g (Pt). The correctness of the new procedure was confirmed by the analysis of geological reference samples—GP-13, UB-N, BHVO-2. The proposed procedure significantly accelerates and simplifies the preparation of geological samples for PGE and Re determination compared to the Carius tube technique.
期刊介绍：
Geochemistry International is a peer reviewed journal that publishes articles on cosmochemistry; geochemistry of magmatic, metamorphic, hydrothermal, and sedimentary processes; isotope geochemistry; organic geochemistry; applied geochemistry; and chemistry of the environment. Geochemistry International provides readers with a unique opportunity to refine their understanding of the geology of the vast territory of the Eurasian continent. The journal welcomes manuscripts from all countries in the English or Russian language.
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