镍铜共催化可持续合成二芳基硫属化合物

IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY
D. Kundu, A. Roy, A. Singha, Subir Panja
{"title":"镍铜共催化可持续合成二芳基硫属化合物","authors":"D. Kundu, A. Roy, A. Singha, Subir Panja","doi":"10.2174/2213346108999210111224631","DOIUrl":null,"url":null,"abstract":"\n\nIn recent times, Nickel has become a powerful alternative transition metal catalyst for performing\ncross-coupling reactions due to its low cost and better sustainability. Thus, a sustainable Nicatalyzed\nC-Se cross coupling has been developed in the presence of catalytic amount of copper iodide\nas co-catalyst. A wide range of substituted diaryl selenides has been synthesized by this Ni-Cu dual\ncatalyzed C-Se cross coupling. The reaction is following an oxidative addition and reductive elimination\npathway where Cu is playing an important role in transmetalation. The mechanism of the reaction\nwas established by several experimental techniques.\n","PeriodicalId":10856,"journal":{"name":"Current Green Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1000,"publicationDate":"2021-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Nickel-copper Co-catalyzed Sustainable Synthesis of Diaryl-chalcogenides\",\"authors\":\"D. Kundu, A. Roy, A. Singha, Subir Panja\",\"doi\":\"10.2174/2213346108999210111224631\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n\\nIn recent times, Nickel has become a powerful alternative transition metal catalyst for performing\\ncross-coupling reactions due to its low cost and better sustainability. Thus, a sustainable Nicatalyzed\\nC-Se cross coupling has been developed in the presence of catalytic amount of copper iodide\\nas co-catalyst. A wide range of substituted diaryl selenides has been synthesized by this Ni-Cu dual\\ncatalyzed C-Se cross coupling. The reaction is following an oxidative addition and reductive elimination\\npathway where Cu is playing an important role in transmetalation. The mechanism of the reaction\\nwas established by several experimental techniques.\\n\",\"PeriodicalId\":10856,\"journal\":{\"name\":\"Current Green Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2021-01-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Current Green Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2174/2213346108999210111224631\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Green Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/2213346108999210111224631","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

近年来,镍由于其低成本和更好的可持续性,已成为进行交叉偶联反应的强大的替代过渡金属催化剂。因此,在催化量的碘化铜作为助催化剂的存在下,开发了一种可持续的NicatalyzedC-Se交叉偶联。用这种Ni-Cu双催化的C-Se交叉偶联反应合成了一系列取代的硒化二芳基硒化物。该反应是在氧化加成和还原消除途径之后进行的,其中Cu在跨催化中起着重要作用。通过几种实验技术确定了反应机理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Nickel-copper Co-catalyzed Sustainable Synthesis of Diaryl-chalcogenides
In recent times, Nickel has become a powerful alternative transition metal catalyst for performing cross-coupling reactions due to its low cost and better sustainability. Thus, a sustainable Nicatalyzed C-Se cross coupling has been developed in the presence of catalytic amount of copper iodide as co-catalyst. A wide range of substituted diaryl selenides has been synthesized by this Ni-Cu dual catalyzed C-Se cross coupling. The reaction is following an oxidative addition and reductive elimination pathway where Cu is playing an important role in transmetalation. The mechanism of the reaction was established by several experimental techniques.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Current Green Chemistry
Current Green Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
4.30
自引率
13.60%
发文量
6
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信