Gary L. N. Smith, Douglas R. Powell, Michelle D. Moser, Richard W. Taylor
{"title":"三个十八元大环二胺具有不同的供体原子和主取代基","authors":"Gary L. N. Smith, Douglas R. Powell, Michelle D. Moser, Richard W. Taylor","doi":"10.1007/s10847-022-01133-6","DOIUrl":null,"url":null,"abstract":"<div><p>The crystal structures are reported for 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane-6,17-dione, (C<sub>12</sub>H<sub>22</sub>N<sub>2</sub>O<sub>6</sub>), (<b>I</b>), dibenzo[e,q][1,4,10,13,7,16] tetraoxadiazacyclooctadecine-6,13-dione, (C<sub>20</sub>H<sub>22</sub>N<sub>2</sub>O<sub>6</sub>), (<b>II</b>) and 1,4-dioxa-10,13-dithia-7,16-diazacyclooctadecane-8,15-dione, (C<sub>12</sub>H<sub>22</sub>N<sub>2</sub>O<sub>4</sub>S<sub>2</sub>), (<b>III</b>). Solid-state structures show different types of hydrogen bonding for all three structures. In <b>I</b>, there are two intermolecular hydrogen bonds between an amide and carbonyl [N–H···O = 2.8206(11) Å and 2.8637(11) Å] and two intermolecular hydrogen bonds between an amide and ether [N–H···O = 2.9570(11) Å and 3.0067(11) Å]. There are two intramolecular hydrogen bonds between amide and ether oxygens [N–H···O = 2.589(3) Å and 2.623(4) Å] in <b>II</b>. Molecule <b>III</b> has a mixture of intramolecular hydrogen bonds between an amide and thioether [N–H···S = 3.0501(18) Å] and intermolecular hydrogen bonds between an amide and carbonyl [N–H···O = 2.835(2) Å].</p></div>","PeriodicalId":638,"journal":{"name":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","volume":null,"pages":null},"PeriodicalIF":2.3000,"publicationDate":"2022-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Three 18-membered macrocyclic diamides with differing donor atoms and backbone substituents\",\"authors\":\"Gary L. N. Smith, Douglas R. Powell, Michelle D. Moser, Richard W. Taylor\",\"doi\":\"10.1007/s10847-022-01133-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The crystal structures are reported for 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane-6,17-dione, (C<sub>12</sub>H<sub>22</sub>N<sub>2</sub>O<sub>6</sub>), (<b>I</b>), dibenzo[e,q][1,4,10,13,7,16] tetraoxadiazacyclooctadecine-6,13-dione, (C<sub>20</sub>H<sub>22</sub>N<sub>2</sub>O<sub>6</sub>), (<b>II</b>) and 1,4-dioxa-10,13-dithia-7,16-diazacyclooctadecane-8,15-dione, (C<sub>12</sub>H<sub>22</sub>N<sub>2</sub>O<sub>4</sub>S<sub>2</sub>), (<b>III</b>). Solid-state structures show different types of hydrogen bonding for all three structures. In <b>I</b>, there are two intermolecular hydrogen bonds between an amide and carbonyl [N–H···O = 2.8206(11) Å and 2.8637(11) Å] and two intermolecular hydrogen bonds between an amide and ether [N–H···O = 2.9570(11) Å and 3.0067(11) Å]. There are two intramolecular hydrogen bonds between amide and ether oxygens [N–H···O = 2.589(3) Å and 2.623(4) Å] in <b>II</b>. Molecule <b>III</b> has a mixture of intramolecular hydrogen bonds between an amide and thioether [N–H···S = 3.0501(18) Å] and intermolecular hydrogen bonds between an amide and carbonyl [N–H···O = 2.835(2) Å].</p></div>\",\"PeriodicalId\":638,\"journal\":{\"name\":\"Journal of Inclusion Phenomena and Macrocyclic Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2022-02-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inclusion Phenomena and Macrocyclic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10847-022-01133-6\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Agricultural and Biological Sciences\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10847-022-01133-6","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Agricultural and Biological Sciences","Score":null,"Total":0}
Three 18-membered macrocyclic diamides with differing donor atoms and backbone substituents
The crystal structures are reported for 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane-6,17-dione, (C12H22N2O6), (I), dibenzo[e,q][1,4,10,13,7,16] tetraoxadiazacyclooctadecine-6,13-dione, (C20H22N2O6), (II) and 1,4-dioxa-10,13-dithia-7,16-diazacyclooctadecane-8,15-dione, (C12H22N2O4S2), (III). Solid-state structures show different types of hydrogen bonding for all three structures. In I, there are two intermolecular hydrogen bonds between an amide and carbonyl [N–H···O = 2.8206(11) Å and 2.8637(11) Å] and two intermolecular hydrogen bonds between an amide and ether [N–H···O = 2.9570(11) Å and 3.0067(11) Å]. There are two intramolecular hydrogen bonds between amide and ether oxygens [N–H···O = 2.589(3) Å and 2.623(4) Å] in II. Molecule III has a mixture of intramolecular hydrogen bonds between an amide and thioether [N–H···S = 3.0501(18) Å] and intermolecular hydrogen bonds between an amide and carbonyl [N–H···O = 2.835(2) Å].
期刊介绍:
The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites.
The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.