Vitus Hupp, Bernhard Schartel, Kerstin Flothmeier, Andreas Hartwig
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With a special focus on the interaction between the single components, one flame retarded tape and one tape without flame retardant are examined in scenarios of emerging and developing fires, along with their bonds with the common materials wood, zinc-plated steel, mineral wool, polycarbonate, and polymethylmethacrylate. The flame retardant significantly improved the flame retardancy of the tape as a free-standing object and yielded a V-2 rating in UL 94 vertical test and raised the Oxygen Index by 5 vol.%. In bonds, or rather laminates, the investigations prove that the choice of carrier and substrates are the factors with the greatest impact on the fire properties and can change the peak of heat release rate and the maximum average rate of heat emission up to 25%. This research yielded a good empirical overall understanding of the fire behavior of adhesive tapes and bonded materials. 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引用次数: 0
摘要
压敏胶带广泛应用于建筑、铁路车辆和汽车等工业领域,其燃烧性能至关重要。然而,在开发和提供阻燃胶带时,往往没有考虑到胶带和粘接材料在燃烧过程中的相互作用,也没有考虑到胶带在不同的防火测试中对粘接部件防火目标的贡献。本出版物提供了胶带及其阻燃性如何影响粘接材料燃烧行为的全面经验知识。重点关注单个组件之间的相互作用,在新出现和正在发展的火灾中,对一种阻燃胶带和一种不含阻燃剂的胶带,以及它们与木材、镀锌钢、矿棉、聚碳酸酯和聚甲基丙烯酸甲酯等常见材料的粘接情况进行了研究。阻燃剂大大提高了胶带作为独立物体的阻燃性,在 UL 94 垂直测试中达到 V-2 级,氧指数提高了 5 Vol.%。研究证明,在粘合剂或层压板中,载体和基材的选择是对阻燃性能影响最大的因素,可改变热释放率峰值和最大平均热释放率达 25%。这项研究对胶带和粘合材料的火灾行为有了一个很好的经验性总体认识。因此,该研究可为胶带制造商和应用者提供指导,帮助他们开发出更具基材针对性的胶带和粘合材料。
Fire behavior of pressure-sensitive adhesive tapes and bonded materials
Pressure-sensitive adhesive tapes are used in several industrial applications such as construction, railway vehicles and the automotive sector, where the burning behavior is of crucial importance. Flame retarded adhesive tapes are developed and provided, however, often without considering the interaction of adhesive tapes and the bonded materials during burning nor the contribution of the tapes to fire protection goal of the bonded components in distinct fire tests. This publication delivers an empirical comprehensive knowledge how adhesive tapes and their flame retardancy effect the burning behavior of bonded materials. With a special focus on the interaction between the single components, one flame retarded tape and one tape without flame retardant are examined in scenarios of emerging and developing fires, along with their bonds with the common materials wood, zinc-plated steel, mineral wool, polycarbonate, and polymethylmethacrylate. The flame retardant significantly improved the flame retardancy of the tape as a free-standing object and yielded a V-2 rating in UL 94 vertical test and raised the Oxygen Index by 5 vol.%. In bonds, or rather laminates, the investigations prove that the choice of carrier and substrates are the factors with the greatest impact on the fire properties and can change the peak of heat release rate and the maximum average rate of heat emission up to 25%. This research yielded a good empirical overall understanding of the fire behavior of adhesive tapes and bonded materials. Thus, it serves as a guide for tape manufacturers and applicants to develop tapes and bonds more substrate specific.
期刊介绍:
Fire and Materials is an international journal for scientific and technological communications directed at the fire properties of materials and the products into which they are made. This covers all aspects of the polymer field and the end uses where polymers find application; the important developments in the fields of natural products - wood and cellulosics; non-polymeric materials - metals and ceramics; as well as the chemistry and industrial applications of fire retardant chemicals.
Contributions will be particularly welcomed on heat release; properties of combustion products - smoke opacity, toxicity and corrosivity; modelling and testing.