埃及偏高岭土增强矿渣生产绿色水泥

Abdeen M. El Nagar
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引用次数: 0

摘要

新的地质聚合物基材料为未来提供了极好的前景;它们不应被视为波特兰水泥的竞争材料,波特兰水泥长期以来一直是参考建筑材料,而是具有一系列重要优势的替代材料。偏高岭土(MK)由高岭土材料以5ºC/分钟的加热速率在750ºC下烧制2小时制成;导致使用(6∶6,wt%)氢氧化钠和硅酸钠的水冷矿渣材料的碱活化地质聚合物的机械和微观结构性能的增强。在本工作中,将加入的MK的比例小于总质量的20%,因为所用的MK非常细,平均孔结构小于30 mµ,如果作为高比例使用,这会阻碍地质聚合反应。固化在100%相对湿度下,温度为38ºC,老化时间为7、14、28和90天。通过XRD、SEM、FTIR、抗压强度和吸水率等测试手段对地质聚合物试样的性能进行了研究。结果表明,与矿渣控制混合物相比,高达15%的偏高岭土混合物的机械性能提高了90天。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Production of Green Cement from Slag Enhanced by Egyptian Metakaolin Materials
New geopolymer-based materials offer excellent perspectives for the future; they should not be regarded as competitive materials for Portland cement, which has been the reference construction material for so long, but as alternative materials with a series of important advantages to be considered. Metakaolin (MK) produced from firing kaolin material up to 750 ºC for 2 h with a heating rate of 5ºC/min; leads to an enhancement in mechanical and microstructural properties of alkali activated geopolymer of water cooled slag material using (6:6, wt%) of sodium hydroxide and sodium silicate. In the present work the ratios of MK which will be added are less than 20% of the total mass, because of the used MK was very fine with average pore structure less than 30 mµ, which hinders the geopolymerization reaction if used as high ratio. Curing was performed under 100% relative humidity at a temperature of 38ºC and ages of 7, 14, 28 & 90 days. The properties of geopolymer specimens have been studied through measurement of XRD, SEM imaging, FTIR, compressive strength and water absorption. Results showed that the mixes of metakaolin up to 15% results in an enhancement in the mechanical properties as compared with slag control mix up to 90 days.
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