MXenes在超级电容器和二次电池中的应用:综述

Xueqin Xu , Li Yang , Wei Zheng , Heng Zhang , Fushuo Wu , Zhihua Tian , Peigen Zhang , ZhengMing Sun
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引用次数: 49

摘要

二维材料由于具有比表面积大、电子输运能垒低、离子扩散路径短等块状材料所不具备的优点而受到人们的广泛关注。这些优点尤其对于电化学储能装置中的电极是可取的。MXenes于2011年首次通过蚀刻其MAX相前体合成,有多种理由代表一种新的2D材料家族。它们在结构和组成上的丰富多样性,以及良好的导电性和亲水性的罕见结合,使它们在整个二维材料世界中脱颖而出。基于这些优势,MXenes在各种技术重要应用中具有很大的前景,特别是在为先进的智能系统开发新的能量存储技术方面,例如便携式和柔性电子设备。在mxene基材料的合成和应用方面已经取得了显著的研究成果。在新的合成路线不断被报道的同时,具有新组成和新结构的MXenes也不断被发现,这无疑将有助于了解MXenes的基本性质和扩大其应用范围。在其储能相关应用方面,为了克服MXenes的固有缺陷,人们从掺杂、结构调整和混合成分合成等方面进行了许多努力。本文综述了MXenes的合成现状及其在超级电容器、金属离子电池和锂硫电池中的应用进展,并分别列出了MXenes在上述三类应用中的典型工作,以供参考和比较。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

MXenes with applications in supercapacitors and secondary batteries: A comprehensive review

MXenes with applications in supercapacitors and secondary batteries: A comprehensive review

Two-dimensional (2D) materials have received tremendous attention because they possess a set of merits not available in bulk materials, such as large specific surface area, low energy barrier for electron transportation and short ion diffusion path. These advantages are desirable especially for the electrodes in electrochemical energy storage devices. MXenes, first synthesized in 2011 by etching their MAX phase precursors, have plural reasons to represent a new family of 2D materials. Their rich diversity in structure and composition together with the uncommon combination of good electrical conductivity and hydrophilicity makes themselves outstand in the whole 2D materials world. Based on these advantages, MXenes hold great promise for various technologically important applications, particularly in developing new energy storage techniques for advanced smart systems, such as portable and flexible electronics. There have been remarkable research achievements in the synthesis and application of MXene-based materials. While new synthesis routes being continuously reported, MXenes with new composition and novel structure have also been routinely discovered, which will undoubtedly help understand the fundamental properties and expand the application scope of MXenes. As for their energy storage-related applications, to cope with the intrinsic weakness of MXenes, many endeavors have been made by doping, structure-tuning and compositing with hybrid ingredients. In this review, the current status of MXenes synthesis and up-to-date progress of their applications in supercapacitors, metal-ion batteries and lithium sulfur batteries are summarized and discussed, and the typical work on the application of MXenes for the aforementioned three categories is respectively tabulated for reference and comparison.

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来源期刊
材料导报:能源(英文)
材料导报:能源(英文) Renewable Energy, Sustainability and the Environment, Nanotechnology
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