{"title":"HNO3和K2CO3制备工业茶渣表面工程可再生碳的电化学储能性能","authors":"Gökçen Akgül, Kürşad Oğuz Oskay, Merve Buldu-Akturk, Ayşenur Karamustafa, Sözer Sözer, Tuğba Bolat Maden, Emre Erdem","doi":"10.3103/S1068375523020084","DOIUrl":null,"url":null,"abstract":"<p>Direct electrical energy storage by supercapacitors is the leading energy storage technology. The performance of supercapacitors depends mainly upon the electrode material constituents. Carbon is the preferred energy storage material for its some main properties such as a large surface area, electrical conductivity, porosity, thermal stability, etc. Sustainable, green, renewable, low-cost and environmentally friendly carbon energy storage materials can be obtained from biomass. A larger surface area and tunable micro-porosity, which are the most important advantages, could be achieved by chemical activation of K<sub>2</sub>CO<sub>3</sub> and HNO<sub>3</sub>. In this work, the effect of K<sub>2</sub>CO<sub>3</sub> and HNO<sub>3</sub> on the porosity and the electrochemical energy storage capacity of carbon derived from biomass made from the industrial tea waste were evaluated. A carbon material with a high performance of energy storage exhibiting 460 F g<sup>–1</sup>, with a surface area of 1261 m<sup>2</sup> g<sup>–1</sup>, could be developed by activation of K<sub>2</sub>CO<sub>3</sub> in the 1 : 1 optimum ratio (w/w). The HNO<sub>3</sub> treatment also increased the capacitance but to a very low degree.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 2","pages":"199 - 209"},"PeriodicalIF":0.9000,"publicationDate":"2023-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrochemical Energy Storage Capacity of Surface Engineered Renewable Carbon Derived from Industrial Tea Waste by HNO3 and K2CO3\",\"authors\":\"Gökçen Akgül, Kürşad Oğuz Oskay, Merve Buldu-Akturk, Ayşenur Karamustafa, Sözer Sözer, Tuğba Bolat Maden, Emre Erdem\",\"doi\":\"10.3103/S1068375523020084\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Direct electrical energy storage by supercapacitors is the leading energy storage technology. The performance of supercapacitors depends mainly upon the electrode material constituents. Carbon is the preferred energy storage material for its some main properties such as a large surface area, electrical conductivity, porosity, thermal stability, etc. Sustainable, green, renewable, low-cost and environmentally friendly carbon energy storage materials can be obtained from biomass. A larger surface area and tunable micro-porosity, which are the most important advantages, could be achieved by chemical activation of K<sub>2</sub>CO<sub>3</sub> and HNO<sub>3</sub>. In this work, the effect of K<sub>2</sub>CO<sub>3</sub> and HNO<sub>3</sub> on the porosity and the electrochemical energy storage capacity of carbon derived from biomass made from the industrial tea waste were evaluated. A carbon material with a high performance of energy storage exhibiting 460 F g<sup>–1</sup>, with a surface area of 1261 m<sup>2</sup> g<sup>–1</sup>, could be developed by activation of K<sub>2</sub>CO<sub>3</sub> in the 1 : 1 optimum ratio (w/w). The HNO<sub>3</sub> treatment also increased the capacitance but to a very low degree.</p>\",\"PeriodicalId\":782,\"journal\":{\"name\":\"Surface Engineering and Applied Electrochemistry\",\"volume\":\"59 2\",\"pages\":\"199 - 209\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2023-05-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surface Engineering and Applied Electrochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.3103/S1068375523020084\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Engineering and Applied Electrochemistry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.3103/S1068375523020084","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Engineering","Score":null,"Total":0}
引用次数: 0
摘要
利用超级电容器直接存储电能是目前领先的储能技术。超级电容器的性能主要取决于电极材料成分。碳具有较大的表面积、导电性、孔隙率、热稳定性等主要特性,是首选的储能材料。生物质可获得可持续、绿色、可再生、低成本、环保的碳储能材料。K2CO3和HNO3的化学活化可以获得更大的表面积和可调的微孔隙度,这是最重要的优点。研究了K2CO3和HNO3对工业茶渣生物质炭的孔隙率和电化学储能能力的影响。K2CO3以1:1的最佳活化比(w/w)可制备出具有460 F - 1、1261 m2 - 1的高性能储能碳材料。HNO3处理也增加了电容量,但增加的程度很低。
Electrochemical Energy Storage Capacity of Surface Engineered Renewable Carbon Derived from Industrial Tea Waste by HNO3 and K2CO3
Direct electrical energy storage by supercapacitors is the leading energy storage technology. The performance of supercapacitors depends mainly upon the electrode material constituents. Carbon is the preferred energy storage material for its some main properties such as a large surface area, electrical conductivity, porosity, thermal stability, etc. Sustainable, green, renewable, low-cost and environmentally friendly carbon energy storage materials can be obtained from biomass. A larger surface area and tunable micro-porosity, which are the most important advantages, could be achieved by chemical activation of K2CO3 and HNO3. In this work, the effect of K2CO3 and HNO3 on the porosity and the electrochemical energy storage capacity of carbon derived from biomass made from the industrial tea waste were evaluated. A carbon material with a high performance of energy storage exhibiting 460 F g–1, with a surface area of 1261 m2 g–1, could be developed by activation of K2CO3 in the 1 : 1 optimum ratio (w/w). The HNO3 treatment also increased the capacitance but to a very low degree.
期刊介绍:
Surface Engineering and Applied Electrochemistry is a journal that publishes original and review articles on theory and applications of electroerosion and electrochemical methods for the treatment of materials; physical and chemical methods for the preparation of macro-, micro-, and nanomaterials and their properties; electrical processes in engineering, chemistry, and methods for the processing of biological products and food; and application electromagnetic fields in biological systems.