2-全氟己基甲基丙烯酸乙酯和2-甲基丙烯酸羟乙酯两亲性双嵌段和无规共聚物溶液的性质及其涂料

IF 1.1 4区化学 Q4 CHEMISTRY, PHYSICAL

Doklady Physical Chemistry Pub Date : 2022-06-20 DOI:10.1134/S0012501622030010

I. V. Blagodatskikh, O. V. Vyshivannaya, K. E. Chekurov, A. I. Barabanova, A. R. Khokhlov

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引用次数: 0

摘要

研究了在混合溶剂中2-(全氟己基)甲基丙烯酸乙酯和2-甲基丙烯酸羟乙酯的两亲二嵌段和无规共聚物溶液的结构与这些溶液处理过的表面的水接触角之间的关系。首次研究了同源共聚物和共聚物在混合溶剂中的溶解度和结构，并利用光散射技术确定了分子溶解度和微相、大相分离区域。用透射电镜对不同溶液形成的薄膜结构进行了表征。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Properties of Solutions of Amphiphilic Diblock and Random Copolymers of 2-Perfluorohexylethyl Methacrylate and 2-Hydroxyethyl Methacrylate and Coatings Based on Them

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Properties of Solutions of Amphiphilic Diblock and Random Copolymers of 2-Perfluorohexylethyl Methacrylate and 2-Hydroxyethyl Methacrylate and Coatings Based on Them

The study addresses the relationship between the structure of solutions of amphiphilic diblock and random copolymers of 2-(perfluorohexyl)ethyl methacrylate and 2-hydroxyethyl methacrylate in mixed solvents and water contact angles of the surfaces treated with these solutions. For the first time, the solubility and the structuring of homo- and copolymers in mixed solvents were studied and the regions of molecular solubility and microphase and macrophase separation were determined by light scattering techniques. The structure of thin films formed from various solutions was characterized by transmission electron microscopy.

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来源期刊

Doklady Physical Chemistry 化学-物理化学

CiteScore

1.50

自引率

0.00%

发文量

审稿时长

6-12 weeks

期刊介绍： Doklady Physical Chemistry is a monthly journal containing English translations of current Russian research in physical chemistry from the Physical Chemistry sections of the Doklady Akademii Nauk (Proceedings of the Russian Academy of Sciences). The journal publishes the most significant new research in physical chemistry being done in Russia, thus ensuring its scientific priority. Doklady Physical Chemistry presents short preliminary accounts of the application of the state-of-the-art physical chemistry ideas and methods to the study of organic and inorganic compounds and macromolecules; polymeric, inorganic and composite materials as well as corresponding processes. The journal is intended for scientists in all fields of chemistry and in interdisciplinary sciences.