Ji Qi , Ziying An , Chuang Li , Xiao Chen , Wenzhen Li , Changhai Liang
{"title":"乙二醇电催化选择性氧化:催化剂的发展和反应机理的简要综述，并与热催化氧化过程进行了比较","authors":"Ji Qi , Ziying An , Chuang Li , Xiao Chen , Wenzhen Li , Changhai Liang","doi":"10.1016/j.coelec.2021.100929","DOIUrl":null,"url":null,"abstract":"<div><p><span><span>As an important water and seawater degradable plastic </span>monomer<span><span>, glycolic acid<span> can be synthesized by selective oxidation of </span></span>ethylene glycol. This review recapitulates recent advances in electrocatalytic ethylene glycol oxidation reaction (EGOR) from the aspects of catalytic performance and reaction mechanism. For catalytic performance evaluation, target product yield and space-time yield are correlated and analyzed for electrocatalytic and thermocatalytic EGOR systems. To elucidate the rationale behind the electrocatalytic selective oxidation of ethylene glycol, previous works using </span></span><em>in situ</em><span><span> Fourier transform infrared spectroscopy, online </span>differential electrochemical mass spectrometry<span>, ion chromatography, and theoretical calculations to investigate EGOR are systematically reviewed. Finally, the advantages of electrocatalytic EGOR are summarized by comparing electrocatalytic and thermocatalytic processes.</span></span></p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"32 ","pages":"Article 100929"},"PeriodicalIF":6.9000,"publicationDate":"2022-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"Electrocatalytic selective oxidation of ethylene glycol: A concise review of catalyst development and reaction mechanism with comparison to thermocatalytic oxidation process\",\"authors\":\"Ji Qi , Ziying An , Chuang Li , Xiao Chen , Wenzhen Li , Changhai Liang\",\"doi\":\"10.1016/j.coelec.2021.100929\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span><span>As an important water and seawater degradable plastic </span>monomer<span><span>, glycolic acid<span> can be synthesized by selective oxidation of </span></span>ethylene glycol. This review recapitulates recent advances in electrocatalytic ethylene glycol oxidation reaction (EGOR) from the aspects of catalytic performance and reaction mechanism. For catalytic performance evaluation, target product yield and space-time yield are correlated and analyzed for electrocatalytic and thermocatalytic EGOR systems. To elucidate the rationale behind the electrocatalytic selective oxidation of ethylene glycol, previous works using </span></span><em>in situ</em><span><span> Fourier transform infrared spectroscopy, online </span>differential electrochemical mass spectrometry<span>, ion chromatography, and theoretical calculations to investigate EGOR are systematically reviewed. Finally, the advantages of electrocatalytic EGOR are summarized by comparing electrocatalytic and thermocatalytic processes.</span></span></p></div>\",\"PeriodicalId\":11028,\"journal\":{\"name\":\"Current Opinion in Electrochemistry\",\"volume\":\"32 \",\"pages\":\"Article 100929\"},\"PeriodicalIF\":6.9000,\"publicationDate\":\"2022-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Current Opinion in Electrochemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S245191032100243X\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Opinion in Electrochemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S245191032100243X","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Electrocatalytic selective oxidation of ethylene glycol: A concise review of catalyst development and reaction mechanism with comparison to thermocatalytic oxidation process
As an important water and seawater degradable plastic monomer, glycolic acid can be synthesized by selective oxidation of ethylene glycol. This review recapitulates recent advances in electrocatalytic ethylene glycol oxidation reaction (EGOR) from the aspects of catalytic performance and reaction mechanism. For catalytic performance evaluation, target product yield and space-time yield are correlated and analyzed for electrocatalytic and thermocatalytic EGOR systems. To elucidate the rationale behind the electrocatalytic selective oxidation of ethylene glycol, previous works using in situ Fourier transform infrared spectroscopy, online differential electrochemical mass spectrometry, ion chromatography, and theoretical calculations to investigate EGOR are systematically reviewed. Finally, the advantages of electrocatalytic EGOR are summarized by comparing electrocatalytic and thermocatalytic processes.
期刊介绍：
The development of the Current Opinion journals stemmed from the acknowledgment of the growing challenge for specialists to stay abreast of the expanding volume of information within their field. In Current Opinion in Electrochemistry, they help the reader by providing in a systematic manner:
1.The views of experts on current advances in electrochemistry in a clear and readable form.
2.Evaluations of the most interesting papers, annotated by experts, from the great wealth of original publications.
In the realm of electrochemistry, the subject is divided into 12 themed sections, with each section undergoing an annual review cycle:
• Bioelectrochemistry • Electrocatalysis • Electrochemical Materials and Engineering • Energy Storage: Batteries and Supercapacitors • Energy Transformation • Environmental Electrochemistry • Fundamental & Theoretical Electrochemistry • Innovative Methods in Electrochemistry • Organic & Molecular Electrochemistry • Physical & Nano-Electrochemistry • Sensors & Bio-sensors •
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