Weicui Liu , Nanping Deng , Gang Wang , Ruru Yu , Xiaoxiao Wang , Bowen Cheng , Jingge Ju , Weimin Kang
{"title":"氟化/掺氟纳米碳基材料在各种电池中的氟化途径、作用机理及应用综述","authors":"Weicui Liu , Nanping Deng , Gang Wang , Ruru Yu , Xiaoxiao Wang , Bowen Cheng , Jingge Ju , Weimin Kang","doi":"10.1016/j.jechem.2023.06.020","DOIUrl":null,"url":null,"abstract":"<div><p>With the popularity and widespread applications of electronics, higher demands are being placed on the performance of battery materials. Due to the large difference in electronegativity between fluorine and carbon atoms, doping fluorine atoms in nanocarbon-based materials is considered an effective way to improve the performance of used battery. However, there is still a blank in the systematic review of the mechanism and research progress of fluorine-doped nanostructured carbon materials in various batteries. In this review, the synthetic routes of fluorinated/fluorine-doped nanocarbon-based (CF<em><sub>x</sub></em>) materials under different fluorine sources and the function mechanism of CF<em><sub>x</sub></em> in various batteries are reviewed in detail. Subsequently, judging from the dependence between the structure and electrochemical performance of nanocarbon sources, the progress of CF<em><sub>x</sub></em> based on different dimensions (0D–3D) for primary battery applications is reviewed and the balance between energy density and power density is critically discussed. In addition, the roles of CF<em><sub>x</sub></em> materials in secondary batteries and their current applications in recent years are summarized in detail to illustrate the effect of introducing F atoms. Finally, we envisage the prospect of CF<em><sub>x</sub></em> materials and offer some insights and recommendations to facilitate the further exploration of CF<em><sub>x</sub></em> materials for various high-performance battery applications.</p></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"85 ","pages":"Pages 363-393"},"PeriodicalIF":13.1000,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Fluoridation routes, function mechanism and application of fluorinated/fluorine-doped nanocarbon-based materials for various batteries: A review\",\"authors\":\"Weicui Liu , Nanping Deng , Gang Wang , Ruru Yu , Xiaoxiao Wang , Bowen Cheng , Jingge Ju , Weimin Kang\",\"doi\":\"10.1016/j.jechem.2023.06.020\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>With the popularity and widespread applications of electronics, higher demands are being placed on the performance of battery materials. Due to the large difference in electronegativity between fluorine and carbon atoms, doping fluorine atoms in nanocarbon-based materials is considered an effective way to improve the performance of used battery. However, there is still a blank in the systematic review of the mechanism and research progress of fluorine-doped nanostructured carbon materials in various batteries. In this review, the synthetic routes of fluorinated/fluorine-doped nanocarbon-based (CF<em><sub>x</sub></em>) materials under different fluorine sources and the function mechanism of CF<em><sub>x</sub></em> in various batteries are reviewed in detail. Subsequently, judging from the dependence between the structure and electrochemical performance of nanocarbon sources, the progress of CF<em><sub>x</sub></em> based on different dimensions (0D–3D) for primary battery applications is reviewed and the balance between energy density and power density is critically discussed. In addition, the roles of CF<em><sub>x</sub></em> materials in secondary batteries and their current applications in recent years are summarized in detail to illustrate the effect of introducing F atoms. Finally, we envisage the prospect of CF<em><sub>x</sub></em> materials and offer some insights and recommendations to facilitate the further exploration of CF<em><sub>x</sub></em> materials for various high-performance battery applications.</p></div>\",\"PeriodicalId\":15728,\"journal\":{\"name\":\"Journal of Energy Chemistry\",\"volume\":\"85 \",\"pages\":\"Pages 363-393\"},\"PeriodicalIF\":13.1000,\"publicationDate\":\"2023-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Energy Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2095495623003662\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Energy\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Energy Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2095495623003662","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Energy","Score":null,"Total":0}
Fluoridation routes, function mechanism and application of fluorinated/fluorine-doped nanocarbon-based materials for various batteries: A review
With the popularity and widespread applications of electronics, higher demands are being placed on the performance of battery materials. Due to the large difference in electronegativity between fluorine and carbon atoms, doping fluorine atoms in nanocarbon-based materials is considered an effective way to improve the performance of used battery. However, there is still a blank in the systematic review of the mechanism and research progress of fluorine-doped nanostructured carbon materials in various batteries. In this review, the synthetic routes of fluorinated/fluorine-doped nanocarbon-based (CFx) materials under different fluorine sources and the function mechanism of CFx in various batteries are reviewed in detail. Subsequently, judging from the dependence between the structure and electrochemical performance of nanocarbon sources, the progress of CFx based on different dimensions (0D–3D) for primary battery applications is reviewed and the balance between energy density and power density is critically discussed. In addition, the roles of CFx materials in secondary batteries and their current applications in recent years are summarized in detail to illustrate the effect of introducing F atoms. Finally, we envisage the prospect of CFx materials and offer some insights and recommendations to facilitate the further exploration of CFx materials for various high-performance battery applications.
期刊介绍:
The Journal of Energy Chemistry, the official publication of Science Press and the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, serves as a platform for reporting creative research and innovative applications in energy chemistry. It mainly reports on creative researches and innovative applications of chemical conversions of fossil energy, carbon dioxide, electrochemical energy and hydrogen energy, as well as the conversions of biomass and solar energy related with chemical issues to promote academic exchanges in the field of energy chemistry and to accelerate the exploration, research and development of energy science and technologies.
This journal focuses on original research papers covering various topics within energy chemistry worldwide, including:
Optimized utilization of fossil energy
Hydrogen energy
Conversion and storage of electrochemical energy
Capture, storage, and chemical conversion of carbon dioxide
Materials and nanotechnologies for energy conversion and storage
Chemistry in biomass conversion
Chemistry in the utilization of solar energy