肟酯:杂环形成的柔性构建块

IF 7.1 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Topics in Current Chemistry Pub Date : 2023-05-18 DOI:10.1007/s41061-023-00431-y

Faeze Yousefnejad, Fatemeh Gholami, Bagher Larijani, Mohammad Mahdavi

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引用次数: 0

摘要

近十年来，肟酯作为一种适用于含-、S-和o型杂环支架合成的构建基、内氧化剂和导向基团受到了广泛的关注。本文综述了近年来在过渡金属和无过渡金属催化条件下肟酯与各种官能团试剂的环化反应的研究进展。此外，还详细解释了这些协议的机制方面。图形抽象

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Oxime Esters: Flexible Building Blocks for Heterocycle Formation

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Oxime Esters: Flexible Building Blocks for Heterocycle Formation

Oxime esters as the applicable building blocks, internal oxidizing agents, and directing groups in the synthesis of –, S-, and O-containing heterocycle scaffolds have gained great attention in the last decade. This review provides an overview of recent advances in the cyclization of oxime esters with various functional group reagents under transition metal and transition metal-free catalyzed conditions. Moreover, the mechanistic aspects of these protocols are explained in detail.

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来源期刊

Topics in Current Chemistry Chemistry-General Chemistry

CiteScore

13.70

自引率

1.20%

发文量

期刊介绍： Topics in Current Chemistry is a journal that presents critical reviews of present and future trends in modern chemical research. It covers all areas of chemical science, including interactions with related disciplines like biology, medicine, physics, and materials science. The articles in this journal are organized into thematic collections, offering a comprehensive perspective on emerging research to non-specialist readers in academia or industry. Each review article focuses on one aspect of the topic and provides a critical survey, placing it in the context of the collection. Selected examples highlight significant developments from the past 5 to 10 years. Instead of providing an exhaustive summary or extensive data, the articles concentrate on methodological thinking. This approach allows non-specialist readers to understand the information fully and presents the potential prospects for future developments.