基于pvdf的含氟聚合物的光诱导原子转移自由基聚合修饰

IF 2 4区工程技术 Q3 ENGINEERING, CHEMICAL

Advances in Polymer Technology Pub Date : 2022-12-21 DOI:10.1155/2022/7798967

Nuo Xu, Guangyu Pan, Hui Zhang, Peng Lu, Lei Shen, Yuguang Li, D. Ji, Jindian Duan, Xin Hu, Chunhua Lu, Zhong-zi Xu, N. Zhu, Kai Guo

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引用次数: 1

摘要

PVDF含氟聚合物的接枝改性已被确定为改善其性能和扩大其应用范围的有效途径。原子转移自由基聚合(ATRP)技术利用重复单元中的C-F和C-Cl键，广泛应用于接枝改性。近年来，与热激活模式相比，光诱导ATRP对聚合过程表现出良好的空间和时间控制。本文综述了光诱导Cu(II)介导的ATRP和有机催化的ATRP在pvdf基含氟聚合物改性方面的进展。提出了含氟聚合物的挑战和机遇，旨在促进含氟聚合物的合成和应用的发展。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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PVDF-Based Fluoropolymer Modifications via Photoinduced Atom Transfer Radical Polymerizations

Graft modifications of PVDF fluoropolymers have been identified as the efficient route to improve the properties and expand the applications. Taking advantage of C-F and C-Cl bonds in the repeat units, atom transfer radical polymerizations (ATRP) were widely used for graft modification. Recently, photoinduced ATRP has shown good spatial and temporal control over the polymerization process in contrast to thermal activation mode. This minireview highlights the progress in PVDF-based fluoropolymer modifications by using photoinduced Cu(II)-mediated ATRP and organocatalyzed ATRP. The challenges and opportunities are proposed with the aim at advancing the development of synthesis and applications of fluoropolymer.

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来源期刊

Advances in Polymer Technology 工程技术-高分子科学

CiteScore

5.50

自引率

0.00%

发文量

审稿时长

9 months

期刊介绍： Advances in Polymer Technology publishes articles reporting important developments in polymeric materials, their manufacture and processing, and polymer product design, as well as those considering the economic and environmental impacts of polymer technology. The journal primarily caters to researchers, technologists, engineers, consultants, and production personnel.