溶液处理太阳能电池接触层用碱土金属硫化物的胶体纳米晶体合成

IF 0.9 4区材料科学 Q3 CRYSTALLOGRAPHY

Zeitschrift Fur Kristallographie-Crystalline Materials Pub Date : 2023-07-25 DOI:10.1515/zkri-2023-0006

Vincent Mauritz, Katharina E. Dehm, Simon P. Hager, Ryan W. Crisp

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引用次数: 0

摘要

摘要为了深入了解碱土金属硫化物作为光电子器件开发的构建块的适用性，对其进行了研究。在油胺中系统地合成了MgS、CaS、SrS和BaS作为胶体颗粒。颗粒大小约为819 纳米，MgS至12.8 对于CaS，纳米，25.0 SrS为nm，21.6 对于BaS为nm。加热合成使用商业上可获得的前体，而不需要复杂的程序。用X射线衍射、椭圆偏振光谱法、紫外-可见分光光度法、扫描电子显微镜和能量色散X射线光谱法研究了其结构和光学性能。

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Colloidal nanocrystal synthesis of alkaline earth metal sulfides for solution-processed solar cell contact layers

Abstract To gain insight into the applicability as building blocks for optoelectronic device development, alkaline earth metal sulfides are investigated. MgS, CaS, SrS, and BaS have been systematically synthesized as colloidal particles in olelyamine. The particle sizes range from around 819 nm for MgS to 12.8 nm for CaS, 25.0 nm for SrS, and 21.6 nm for BaS. The heat-up synthesis uses commerically available precursors without complicated procedures. The structural and optical properties are investigated with X-ray diffraction, spectroscopic ellipsometry, UV–vis spectrophotometry, scanning electron microscopy, and energy dispersive X-ray spectroscopy.

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来源期刊

Zeitschrift Fur Kristallographie-Crystalline Materials CRYSTALLOGRAPHY-

CiteScore

2.00

自引率

16.70%

发文量

期刊介绍： Zeitschrift für Kristallographie – Crystalline Materials was founded in 1877 by Paul von Groth and is today one of the world’s oldest scientific journals. It offers a place for researchers to present results of their theoretical experimental crystallographic studies. The journal presents significant results on structures and on properties of organic/inorganic substances with crystalline character, periodically ordered, modulated or quasicrystalline on static and dynamic phenomena applying the various methods of diffraction, spectroscopy and microscopy.