用于金属离子和金属硫电池的MXenes:合成、性能和电化学

Siyang Liu, Zihui Song, Xin Jin, Runyue Mao, Tianpeng Zhang, Fangyuan Hu
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引用次数: 14

摘要

2011年,发现了一类新的二维材料;2012年之后,他们开始担心;2017年,材料的“淘金热”被触发,而它们恰恰是MXenes。二维MXenes是一类新型的过渡金属碳化物、碳氮化物和氮化物,由于其独特的二维结构、丰富的表面化学性质以及优异的物理和电化学性能,已成为新兴电池体系领域的明星和前沿研究材料。综述了MXene材料的合成技术和性能的最新进展,并对其在碱离子(Li+, Na+, K+)存储、锂硫(Li -s)电池、钠硫(Na -s)电池和金属阳极保护等电化学储能方面的应用进行了详细讨论。重点研究了MXenes的纳米微观结构设计,并将其作为电极、多功能组件、S宿主、改性隔膜和金属阳极保护层。最后对MXene材料的合成、结构、性能、分析和生产等方面的研究方向进行了展望。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

MXenes for metal-ion and metal-sulfur batteries: Synthesis, properties, and electrochemistry

MXenes for metal-ion and metal-sulfur batteries: Synthesis, properties, and electrochemistry

In 2011, a new class of 2D materials was discovered; after 2012, they began to be concerned; in 2017, the “gold rush” of the materials was triggered, and they are exactly MXenes. 2D MXenes, a new class of transition metal carbides, carbonitrides and nitrides, have become the star and cutting-edge research materials in the field of emerging batteries systems due to their unique 2D structure, abundant surface chemistry, and excellent physical and electrochemical properties. This review focuses on the MXene materials and summarizes the recent advancements in the synthesis techniques and properties, in addition to a detailed discussion on the electrochemical energy storage applications, including alkali-ion (Li+, Na+, K+) storage, lithium-sulfur (Li–S) batteries, sodium-sulfur (Na–S) batteries, and metal anode protection. Special attentions are given to the elaborate design of nano-micro structures of MXenes for the various roles as electrodes, multifunctional components, S hosts, modified separators, and metal anode protective layers. The paper ends with a prospective summary of the promising research directions in terms of synthesis, structure, properties, analysis, and production on MXene materials.

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来源期刊
材料导报:能源(英文)
材料导报:能源(英文) Renewable Energy, Sustainability and the Environment, Nanotechnology
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