基于季铵阳离子的新型三碘离子液体的合成及其在温和无溶剂条件下用作溶剂试剂的研究

IF 1.3 3区化学 Q3 CHEMISTRY, ORGANIC

Heterocyclic Communications Pub Date : 2022-01-01 DOI:10.1515/hc-2022-0006

Mahnaz Sakhdari, Nadiya Koukabi, M. Zolfigol

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引用次数: 0

摘要

摘要本文首次合成了N,N,N-三乙基-3-碘丙烷-1-三碘化胺[N2223I] [I3]，并与H2O2(35%)结合，作为试剂和溶剂将芳香族化合物转化为相应的碘衍生物。碘化是在没有有机溶剂的情况下完成的，在大多数情况下，水是唯一使用的提取溶剂。耗用的试剂N,N,N-三乙基-3-碘丙-1-碘化胺可轻松回收。图形抽象

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Synthesis of novel triiodide ionic liquid based on quaternary ammonium cation and its use as a solvent reagent under mild and solvent-free conditions

Abstract In this article, for the first time, N,N,N-triethyl-3-iodopropan-1-aminium triiodide [N2223I] [I3] was synthesized and utilized as both a reagent and a solvent in combination with H2O2 (35%) to convert aromatic compounds into their corresponding iodo derivatives. The iodination was accomplished in the absence of organic solvents, and in most instances, water was the sole extraction solvent used. The consumed reagent N,N,N-triethyl-3-iodopropan-1-aminium iodide was comfortably recycled. Graphical abstract

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来源期刊

Heterocyclic Communications 化学-有机化学

CiteScore

3.80

自引率

4.30%

发文量

审稿时长

1.4 months

期刊介绍： Heterocyclic Communications (HC) is a bimonthly, peer-reviewed journal publishing preliminary communications, research articles, and reviews on significant developments in all phases of heterocyclic chemistry, including general synthesis, natural products, computational analysis, considerable biological activity and inorganic ring systems. Clear presentation of experimental and computational data is strongly emphasized. Heterocyclic chemistry is a rapidly growing field. By some estimates original research papers in heterocyclic chemistry have increased to more than 60% of the current organic chemistry literature published. This explosive growth is even greater when considering heterocyclic research published in materials science, physical, biophysical, analytical, bioorganic, pharmaceutical, medicinal and natural products journals. There is a need, therefore, for a journal dedicated explicitly to heterocyclic chemistry and the properties of heterocyclic compounds.