一些基本的化学概念是如何通过算术、几何和调和的方法联系起来的

IF 1.8 3区 化学 Q1 HISTORY & PHILOSOPHY OF SCIENCE
Francesco Di Giacomo
{"title":"一些基本的化学概念是如何通过算术、几何和调和的方法联系起来的","authors":"Francesco Di Giacomo","doi":"10.1007/s10698-023-09466-x","DOIUrl":null,"url":null,"abstract":"<div><p>Examples are given of applications by Pauling, Mulliken, Marcus and G.E.Kimball of the three Pythagorian means to formulate the scales of electronegativity of the elements, to the calculations of rate constants of electron transfer cross-reactions, to the calculation of the observed rate constant as function of activation and diffusion rate constants in the case of mixed reaction-diffusion rates and to the calculation of the effective diffusion coefficient in solution of a salt AB as a whole from the diffusion coefficients of the ions in which it dissociates.</p></div>","PeriodicalId":568,"journal":{"name":"Foundations of Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2023-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"On how some fundamental chemical concepts are correlated by arithmetic, geometric and harmonic means\",\"authors\":\"Francesco Di Giacomo\",\"doi\":\"10.1007/s10698-023-09466-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Examples are given of applications by Pauling, Mulliken, Marcus and G.E.Kimball of the three Pythagorian means to formulate the scales of electronegativity of the elements, to the calculations of rate constants of electron transfer cross-reactions, to the calculation of the observed rate constant as function of activation and diffusion rate constants in the case of mixed reaction-diffusion rates and to the calculation of the effective diffusion coefficient in solution of a salt AB as a whole from the diffusion coefficients of the ions in which it dissociates.</p></div>\",\"PeriodicalId\":568,\"journal\":{\"name\":\"Foundations of Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2023-04-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Foundations of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10698-023-09466-x\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"HISTORY & PHILOSOPHY OF SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Foundations of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10698-023-09466-x","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"HISTORY & PHILOSOPHY OF SCIENCE","Score":null,"Total":0}
引用次数: 0

摘要

文中举例说明了鲍林、穆利肯、马库斯和金博尔用毕达哥拉斯三种方法来表示元素电负性的尺度,并计算了电子转移交叉反应的速率常数。在混合反应扩散速率的情况下,计算观察到的速率常数作为活化速率常数和扩散速率常数的函数,以及从盐解离的离子的扩散系数计算整个盐AB溶液中的有效扩散系数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
On how some fundamental chemical concepts are correlated by arithmetic, geometric and harmonic means

Examples are given of applications by Pauling, Mulliken, Marcus and G.E.Kimball of the three Pythagorian means to formulate the scales of electronegativity of the elements, to the calculations of rate constants of electron transfer cross-reactions, to the calculation of the observed rate constant as function of activation and diffusion rate constants in the case of mixed reaction-diffusion rates and to the calculation of the effective diffusion coefficient in solution of a salt AB as a whole from the diffusion coefficients of the ions in which it dissociates.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Foundations of Chemistry
Foundations of Chemistry HISTORY & PHILOSOPHY OF SCIENCE-
自引率
22.20%
发文量
35
期刊介绍: Foundations of Chemistry is an international journal which seeks to provide an interdisciplinary forum where chemists, biochemists, philosophers, historians, educators and sociologists with an interest in foundational issues can discuss conceptual and fundamental issues which relate to the `central science'' of chemistry. Such issues include the autonomous role of chemistry between physics and biology and the question of the reduction of chemistry to quantum mechanics. The journal will publish peer-reviewed academic articles on a wide range of subdisciplines, among others: chemical models, chemical language, metaphors, and theoretical terms; chemical evolution and artificial self-replication; industrial application, environmental concern, and the social and ethical aspects of chemistry''s professionalism; the nature of modeling and the role of instrumentation in chemistry; institutional studies and the nature of explanation in the chemical sciences; theoretical chemistry, molecular structure and chaos; the issue of realism; molecular biology, bio-inorganic chemistry; historical studies on ancient chemistry, medieval chemistry and alchemy; philosophical and historical articles; and material of a didactic nature relating to all topics in the chemical sciences. Foundations of Chemistry plans to feature special issues devoted to particular themes, and will contain book reviews and discussion notes. Audience: chemists, biochemists, philosophers, historians, chemical educators, sociologists, and other scientists with an interest in the foundational issues of science.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信