{"title":"水合物和成分耦合井筒模拟器:了解油气生产中伴生盐水对水合物的抑制作用","authors":"F. Coelho, K. Sepehrnoori, O. Ezekoye","doi":"10.2118/206716-pa","DOIUrl":null,"url":null,"abstract":"\n Hydrates are ice-like solids composed of a water-based lattice “encaging” gas molecules. They form under conditions of high pressure and low temperature. In the oil and gas industry, where these conditions are easily met, hydrate formation may cause pipe blockages and severe financial implications, making its prevention (and remediation) one of the main flow-assurance concerns. Desired hydrate inhibition may come from electrolytes naturally dissolved in the water that is produced in conjunction with the hydrocarbon stream, or alcohols can be deliberately injected for such a purpose. When trying to predict hydrate conditions in real-world production systems, computer simulation should ideally integrate hydrate and multiphase-flow calculations. Failing to do so [by performing a decoupled analysis with a flow simulator and a separate pressure/volume/temperature (PVT) package for example] may generate misleading results under certain flow conditions. This paper presents an integrated wellbore simulator to deal with this issue. A hydrate model is added to verify hydrate formation for specific pressure, temperature, and composition of each gridblock. Integration with a geochemical package allows consideration of electrolyte inhibition coming from the associated brine. After successfully comparing results with the available simulators and the experimental data, it is demonstrated that when flowing gas/water ratios (GWRs) exceed 105 scf/STB, water condensation throughout the flow may dilute the beneficial effect arising from the brine composition, thus reducing electrolyte inhibition. Conversely, mineral precipitation along the flow path has shown a nearly negligible impact on this effect.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2021-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"A Coupled Hydrate and Compositional Wellbore Simulator: Understanding Hydrate Inhibition from Associated Brines in Oil and Gas Production\",\"authors\":\"F. Coelho, K. Sepehrnoori, O. Ezekoye\",\"doi\":\"10.2118/206716-pa\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n Hydrates are ice-like solids composed of a water-based lattice “encaging” gas molecules. They form under conditions of high pressure and low temperature. In the oil and gas industry, where these conditions are easily met, hydrate formation may cause pipe blockages and severe financial implications, making its prevention (and remediation) one of the main flow-assurance concerns. Desired hydrate inhibition may come from electrolytes naturally dissolved in the water that is produced in conjunction with the hydrocarbon stream, or alcohols can be deliberately injected for such a purpose. When trying to predict hydrate conditions in real-world production systems, computer simulation should ideally integrate hydrate and multiphase-flow calculations. Failing to do so [by performing a decoupled analysis with a flow simulator and a separate pressure/volume/temperature (PVT) package for example] may generate misleading results under certain flow conditions. This paper presents an integrated wellbore simulator to deal with this issue. A hydrate model is added to verify hydrate formation for specific pressure, temperature, and composition of each gridblock. Integration with a geochemical package allows consideration of electrolyte inhibition coming from the associated brine. After successfully comparing results with the available simulators and the experimental data, it is demonstrated that when flowing gas/water ratios (GWRs) exceed 105 scf/STB, water condensation throughout the flow may dilute the beneficial effect arising from the brine composition, thus reducing electrolyte inhibition. Conversely, mineral precipitation along the flow path has shown a nearly negligible impact on this effect.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2021-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.2118/206716-pa\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.2118/206716-pa","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A Coupled Hydrate and Compositional Wellbore Simulator: Understanding Hydrate Inhibition from Associated Brines in Oil and Gas Production
Hydrates are ice-like solids composed of a water-based lattice “encaging” gas molecules. They form under conditions of high pressure and low temperature. In the oil and gas industry, where these conditions are easily met, hydrate formation may cause pipe blockages and severe financial implications, making its prevention (and remediation) one of the main flow-assurance concerns. Desired hydrate inhibition may come from electrolytes naturally dissolved in the water that is produced in conjunction with the hydrocarbon stream, or alcohols can be deliberately injected for such a purpose. When trying to predict hydrate conditions in real-world production systems, computer simulation should ideally integrate hydrate and multiphase-flow calculations. Failing to do so [by performing a decoupled analysis with a flow simulator and a separate pressure/volume/temperature (PVT) package for example] may generate misleading results under certain flow conditions. This paper presents an integrated wellbore simulator to deal with this issue. A hydrate model is added to verify hydrate formation for specific pressure, temperature, and composition of each gridblock. Integration with a geochemical package allows consideration of electrolyte inhibition coming from the associated brine. After successfully comparing results with the available simulators and the experimental data, it is demonstrated that when flowing gas/water ratios (GWRs) exceed 105 scf/STB, water condensation throughout the flow may dilute the beneficial effect arising from the brine composition, thus reducing electrolyte inhibition. Conversely, mineral precipitation along the flow path has shown a nearly negligible impact on this effect.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.