炔烃/烯烃-羰基催化复分解:迈向绿色有机合成

IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY
Aniruddha Das, Soumen Sarkar, Baitan Chakraborty, A. Kar, U. Jana
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引用次数: 14

摘要

通过羰基和烯烃或炔烃之间的复分解反应构建碳-碳键由于其高的原子经济性和高效性而引起了有机化学界的极大兴趣。在这方面,羰基-炔烃复分解得到了很好的发展,并广泛应用于有机合成中,在催化路易斯酸或Brønsted酸的存在下,原子有效地构建各种碳环和杂环。另一方面,烯羰基复分解是最近发展起来的,并且在有机化学领域中一直是一个非常重要的话题,因为它们具有吸引人的性质,包括金属介导的、不含金属的分子内复分解、光化学复分解、路易斯酸介导的闭环复分解、开环复分解和交叉复分解。这篇综述涵盖了复杂分子、天然产物和药物合成中羰基-炔烃和羰基-烯烃复分解反应的大部分策略,并概述了具有高原子经济性和环境和生态良性反应条件的复分解反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Catalytic Alkyne/Alkene-Carbonyl Metathesis: Towards the Development of Green Organic Synthesis
The construction of carbon-carbon bond through the metathesis reactions between carbonyls and olefins or alkynes has attracted significant interest in organic chemistry due to its high atomeconomy and efficiency. In this regard, carbonyl–alkyne metathesis is well developed and widely used in organic synthesis for the atom-efficient construction of various carbocycles and heterocycles in the presence of catalytic Lewis acids or Brønsted acids. On the other hand, alkene-carbonyl metathesis is recently developed and has been a topic of great importance in the field of organic chemistry because they possess attractive qualities involving metal-mediated, metal-free intramolecular, photochemical, Lewis acid-mediated ring-closing metathesis, ring-opening metathesis and cross-metathesis. This review covers most of the strategies of carbonyl–alkyne and carbonyl–olefin metathesis reactions in the synthesis of complex molecules, natural products and pharmaceuticals as well as provides an overview of exploration of the metathesis reactions with high atom-economy as well as environmentally and ecologically benign reaction conditions.
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来源期刊
Current Green Chemistry
Current Green Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
4.30
自引率
13.60%
发文量
6
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