{"title":"剪切条件下聚电解质溶液中的链动力学：流变NMR研究","authors":"Sascha Bartosch, Benjamin Kohn, Ulrich Scheler","doi":"10.1007/s00723-023-01598-9","DOIUrl":null,"url":null,"abstract":"<div><p>Rheological nuclear magnetic resonance (NMR) has been applied to study the effect of shear on the chain dynamics in a solution of a linear poly(sodium 4-styrenesulfonate). Information on the chain dynamics of poly(sodium 4-styrenesulfonate) sheared in a narrow-gap concentric double cylinder cell is inferred from the NMR transverse relaxation <i>T</i><sub>2</sub> for a concentration in the semidilute-entangled and in the concentrated regime. In the semidilute-entangled concentration enhanced relaxation is observed. In the concentrated regime signatures of a loss of entanglements are seen with increasing <i>T</i><sub>2</sub> and a decreasing fraction of the polymer showing restricted motion. The effect is enhanced when the electrostatic interaction along the polymer chain is reduced by the addition of NaCl.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"54 11-12","pages":"1533 - 1541"},"PeriodicalIF":1.1000,"publicationDate":"2023-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00723-023-01598-9.pdf","citationCount":"0","resultStr":"{\"title\":\"Chain Dynamics in a Polyelectrolyte Solution Under Shear: A Rheological NMR Investigation\",\"authors\":\"Sascha Bartosch, Benjamin Kohn, Ulrich Scheler\",\"doi\":\"10.1007/s00723-023-01598-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Rheological nuclear magnetic resonance (NMR) has been applied to study the effect of shear on the chain dynamics in a solution of a linear poly(sodium 4-styrenesulfonate). Information on the chain dynamics of poly(sodium 4-styrenesulfonate) sheared in a narrow-gap concentric double cylinder cell is inferred from the NMR transverse relaxation <i>T</i><sub>2</sub> for a concentration in the semidilute-entangled and in the concentrated regime. In the semidilute-entangled concentration enhanced relaxation is observed. In the concentrated regime signatures of a loss of entanglements are seen with increasing <i>T</i><sub>2</sub> and a decreasing fraction of the polymer showing restricted motion. The effect is enhanced when the electrostatic interaction along the polymer chain is reduced by the addition of NaCl.</p></div>\",\"PeriodicalId\":469,\"journal\":{\"name\":\"Applied Magnetic Resonance\",\"volume\":\"54 11-12\",\"pages\":\"1533 - 1541\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2023-08-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s00723-023-01598-9.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Magnetic Resonance\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00723-023-01598-9\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Magnetic Resonance","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1007/s00723-023-01598-9","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
Chain Dynamics in a Polyelectrolyte Solution Under Shear: A Rheological NMR Investigation
Rheological nuclear magnetic resonance (NMR) has been applied to study the effect of shear on the chain dynamics in a solution of a linear poly(sodium 4-styrenesulfonate). Information on the chain dynamics of poly(sodium 4-styrenesulfonate) sheared in a narrow-gap concentric double cylinder cell is inferred from the NMR transverse relaxation T2 for a concentration in the semidilute-entangled and in the concentrated regime. In the semidilute-entangled concentration enhanced relaxation is observed. In the concentrated regime signatures of a loss of entanglements are seen with increasing T2 and a decreasing fraction of the polymer showing restricted motion. The effect is enhanced when the electrostatic interaction along the polymer chain is reduced by the addition of NaCl.
期刊介绍：
Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields.
The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.
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