Investigation on the temperature-dependent diffusion growth of intermetallic compounds in the Mg-Al-Zn system: Experiment and modeling

With the rapid development of Mg alloys, deeper understanding to the thermodynamic and diffusional kinetic behavior of intermetallic compounds (IMCs) is important for studying the effect of alloying elements to the microstructure evolution. Specially, a systematic quantitative investigation on the diffusional growth of IMCs is of great necessity. However, the works studying the elemental diffusion behaviors of multiple-element IMCs are rare in magnesium alloy systems. The current work takes the ternary Mg-Al-Zn system as research target, and combines the diffusion couple technique, phase stability diagrams, in-situ observation technique and numerical inverse method to investigate the temperature-dependent kinetic coefficients. The parabolic growth constant (PGC) and interdiffusion coefficients for Mg solid-solution phase and γ-Mg₁₇Al₁₂, β-Mg₂Al₃, ε-Mg₂₃Al₃₀, MgZn₂, Mg₂Zn₃, τ-Mg₃₂(Zn, Al)₄₉ and ϕ-Mg₅Zn₂Al₂ IMCs in the Mg-Al-Zn alloy system are determined. By comparing the current experimental with calculation results, the rate-controlling factor of the temperature-dependent diffusion growth of ϕ, τ and ε ternary IMCs in the Mg-Al-Zn system is further discussed in detail.