{"title":"球磨负载铜锰氧化物的日本雪松炭的CO氧化性能","authors":"Yukuo Fujita, T. Takase, Takashi Asada","doi":"10.2488/jwrs.66.67","DOIUrl":null,"url":null,"abstract":"In this work, the Cu-Mn oxide modeled on hopcalite is used as CO oxidation catalyst. The Cu-Mn oxide was loaded on Japanese cedar charcoal for improving its CO oxidation performance by increasing the active area of the metal. Herein, the Japanese cedar charcoal loaded with the Cu-Mn oxide (CMC) was prepared as follows. First, the Cu-Mn oxide precursor obtained using a coprecipitation method was loaded on Japanese cedar sawdust using a ball mill, and then this loaded sawdust was carbonized. Furthermore, the performance of the CMC for CO oxidation in H 2 -rich gas was evaluated. The difference in the catalyst activity was dependent on the types of metal salts used for the sample preparation, the molar ratio of Cu and Mn, and the carbonization temperature. The CO oxidation performance of the CMC increased with KMnO 4 treatment. The treated CMC did not reduce the concentration of H 2 . Hence, the CMC is assumed to be useful as a CO oxidation catalyst for a fuel cell. ball mill, supported catalyst.","PeriodicalId":49800,"journal":{"name":"Mokuzai Gakkaishi","volume":" ","pages":""},"PeriodicalIF":0.1000,"publicationDate":"2020-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"CO Oxidation Performance of Japanese Cedar Charcoal Loaded with Copper-manganese Oxide Using a Ball Mill\",\"authors\":\"Yukuo Fujita, T. Takase, Takashi Asada\",\"doi\":\"10.2488/jwrs.66.67\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this work, the Cu-Mn oxide modeled on hopcalite is used as CO oxidation catalyst. The Cu-Mn oxide was loaded on Japanese cedar charcoal for improving its CO oxidation performance by increasing the active area of the metal. Herein, the Japanese cedar charcoal loaded with the Cu-Mn oxide (CMC) was prepared as follows. First, the Cu-Mn oxide precursor obtained using a coprecipitation method was loaded on Japanese cedar sawdust using a ball mill, and then this loaded sawdust was carbonized. Furthermore, the performance of the CMC for CO oxidation in H 2 -rich gas was evaluated. The difference in the catalyst activity was dependent on the types of metal salts used for the sample preparation, the molar ratio of Cu and Mn, and the carbonization temperature. The CO oxidation performance of the CMC increased with KMnO 4 treatment. The treated CMC did not reduce the concentration of H 2 . Hence, the CMC is assumed to be useful as a CO oxidation catalyst for a fuel cell. ball mill, supported catalyst.\",\"PeriodicalId\":49800,\"journal\":{\"name\":\"Mokuzai Gakkaishi\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.1000,\"publicationDate\":\"2020-04-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Mokuzai Gakkaishi\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.2488/jwrs.66.67\",\"RegionNum\":4,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, PAPER & WOOD\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mokuzai Gakkaishi","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.2488/jwrs.66.67","RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, PAPER & WOOD","Score":null,"Total":0}
CO Oxidation Performance of Japanese Cedar Charcoal Loaded with Copper-manganese Oxide Using a Ball Mill
In this work, the Cu-Mn oxide modeled on hopcalite is used as CO oxidation catalyst. The Cu-Mn oxide was loaded on Japanese cedar charcoal for improving its CO oxidation performance by increasing the active area of the metal. Herein, the Japanese cedar charcoal loaded with the Cu-Mn oxide (CMC) was prepared as follows. First, the Cu-Mn oxide precursor obtained using a coprecipitation method was loaded on Japanese cedar sawdust using a ball mill, and then this loaded sawdust was carbonized. Furthermore, the performance of the CMC for CO oxidation in H 2 -rich gas was evaluated. The difference in the catalyst activity was dependent on the types of metal salts used for the sample preparation, the molar ratio of Cu and Mn, and the carbonization temperature. The CO oxidation performance of the CMC increased with KMnO 4 treatment. The treated CMC did not reduce the concentration of H 2 . Hence, the CMC is assumed to be useful as a CO oxidation catalyst for a fuel cell. ball mill, supported catalyst.